Catena-Poly[[chloro(1,10-phenanthroline-K2N,N')copper(II)]- mu-imidazolato-K2N: N']

In the polymeric title compound, [Cu(im)Cl(phen)n, where im is the imidazolate anion (C3H3N2) and phen is 1,10-phenanthroline (C12H8N2), each CuII ion is five-coordinated by four basal N atoms (two from two different im anions and two from one phen ligand) and one axial Cl atom, in a distorted squar...

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Bibliographic Details
Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2004-11, Vol.60 (11), p.m575-m577
Main Authors: Hu, Mao-Lin, Cai, Xiao-Qing, Shi, Qian, Cheng, Ya-Qian
Format: Article
Language:English
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Summary:In the polymeric title compound, [Cu(im)Cl(phen)n, where im is the imidazolate anion (C3H3N2) and phen is 1,10-phenanthroline (C12H8N2), each CuII ion is five-coordinated by four basal N atoms (two from two different im anions and two from one phen ligand) and one axial Cl atom, in a distorted square-pyramidal coordination geometry. Moreover, each im anion bridges two identical {CuCl(phen)}+ cations through its two N atoms, resulting in a one-dimensional zigzag chain along the crystallographic a axis. In addition, pairs of adjacent chains are staggered by pir-pir interactions, generating a two-dimensional layer, and neighbouring layers are further linked by two different kinds of C-H. Cl interactions, producing a three-dimensional network.
ISSN:0108-2701