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Dye-sensitized TiO2 solar cells using polymer gel electrolytes based on PVdF-HFP

The open-circuit voltage increases substantially and stability of dye-sensitized TiO2 solar cells is improved when polymer gel containing poly(vinylidenefluoride-co-hexafluoropropylene) (PVdF-HFP) in N-methyl-2-pyrrolidone replaces commonly used solvents such as acetonitrile (ACN) and 3-methoxypropi...

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Bibliographic Details
Published in:Journal of the Electrochemical Society 2004, Vol.151 (7), p.E257-E260
Main Authors: MAN GU KANG, KWANG MAN KILN, KWANG SUN RYU, SOON HO CHANG, PARK, Nam-Gyu, JIN SUP HONG, KIM, Kang-Jin
Format: Article
Language:English
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Summary:The open-circuit voltage increases substantially and stability of dye-sensitized TiO2 solar cells is improved when polymer gel containing poly(vinylidenefluoride-co-hexafluoropropylene) (PVdF-HFP) in N-methyl-2-pyrrolidone replaces commonly used solvents such as acetonitrile (ACN) and 3-methoxypropionitrile (MPN). The energy conversion efficiency of the cell with 6 wt % PVdF-HFP is comparable to that obtainable in ACN and in MPN. The promising effect of PVdF-HFP as a gelator is attributed to its interaction with Li+ ions.
ISSN:0013-4651
1945-7111
DOI:10.1149/1.1759698