Electron beam initiated modification of acrylic elastomer in presence of polyfunctional monomers

• Published in: Radiation physics and chemistry (Oxford, England : 1993) England : 1993), 2004-12, Vol.71 (5), p.1045-1058
• Main Authors: Vijayabaskar, V., Bhattacharya, S., Tikku, V.K., Bhowmick, Anil K.
• Format: Article
• Language: English
• Subjects: Acrylic rubber; Charlesby–Pinner plot; FTIR; Gel fraction; Infrared spectroscopy; Linear energy transfer (LET); Mechanical properties
• ISSN: 0969-806X; 1879-0895
• DOI: 10.1016/j.radphyschem.2003.11.006

The structural changes of an acrylic rubber (ACM) in presence and absence of polyfunctional monomers like trimethylolpropane triacrylate, tripropyleneglycol diacrylate, trimethylolmethane tetraacrylate and trimethylolpropane trimethacrylate at different doses of electron beam (EB) irradiations were investigated with the help of FTIR spectroscopy (in the attenuated total reflectance mode) and sol–gel analysis. As the radiation dose increases, the concentration of carbonyl group increases in the ACM rubber due to aerial oxidation. This is corroborated from the increase in the absorbance values at 1734 and 1160 cm −1, which are due to carbonyl and C–O–C stretching frequencies, respectively. The increase in crosslinking is revealed by the increase in percentage gel content with radiation dose. The lifetime of spurs formed and the critical dose, an important criterion for overlapping of spurs have been determined for both grafted and ungrafted ACM rubber using a mathematical model. The predominance of crosslinking by electronic stopping with energetic EB projectile and the increase in effective radius of crosslinking have also been verified by this model. The doses at which the synergistic occurrence of both dislinking and endlinking steps originate have been calculated using linear energy transfer of EB. The ratio of scissioning to crosslinking for ACM rubber has been determined by using Charlesby–Pinner equation. The mechanical properties have been studied for different modified and unmodified systems and the tensile strength is found to increase with grafting of polyfunctional monomers.