Fabrication of copper molybdate nanoflower combined polymeric graphitic carbon nitride heterojunction for water depollution: Synergistic photocatalytic performance and mechanism insight

• Published in: Environmental research 2023-09, Vol.233, p.116428-116428, Article 116428
• Main Authors: Kasirajan, Prakash, Karunamoorthy, Saravanakumar, Velluchamy, Muthuraj, Subramaniam, Kalidass, Park, Chang Min, Sundaram, Ganesh Babu
• Format: Article
• Language: English
• Subjects: antibiotics; carbon nitride; Ciprofloxacin; dyes; graphene; molybdates; nanocomposites; nanoflowers; photocatalysis; Photocatalyst; photocatalysts; Polymeric g-C3N4; polymers; Rhodamine B; rhodamines; species; toxicity; Visible light; wastewater treatment
• ISSN: 0013-9351; 1096-0953
• DOI: 10.1016/j.envres.2023.116428

In the scope, developed a novel copper molybdate decorated polymeric graphitic carbon nitride (CuMoO4@g-C3N4 or CMC) heterojunction nanocomposite in an easy solvothermal environment for the first time. The synthesized CMC improved the photocatalytic degradation of an antibiotic drug [ciprofloxacin (CIP)] and organic dye [Rhodamine B (RhB)]. Consequently, the CMC demonstrates a marvelous crystalline nature with ∼26 nm size, as obtained from XRD analysis. Besides, the surface morphology studies confirm the large-scale construction of flower-like CMC with a typical size of 10–15 nm. The CMC showed efficient catalytic activity for both the pollutants, achieving the degradation of 98% for RhB and 97% for CIP in 35 and 60 min, respectively. The reaction parameters including the concentration of pollutants, catalyst dosages, and scavengers are optimized for the best photocatalytic results. Notably, the trapping tests showed that the •OH and O2•− radicals are the primary oxidative species liable for the photocatalytic process. The recyclability test of the photocatalyst infers that the photocatalyst is highly stable up to the fifth recycle. Our work affords an efficient and ideal path to constructing the new g-C3N4-based architected photocatalyst for toxic wastewater treatment in the near future. •The CuMoO4@g-C3N4 heterojunction was facilely prepared via simple solvothermal treatment.•The CuMoO4@g-C3N4 exhibits highest catalytic activity in degradation of different carcinogenic pollutants.•Synergistic effect improves photocatalytic performance of CuMoO4@g-C3N4.•Influencing factors of numerous physico-chemical parameters were optimized.