Investigation of physical properties and carbon dioxide solubility in tetramethylammonium bromide and tetraethylammonium bromide ionic liquids solutions

• Published in: Chemosphere (Oxford) 2023-10, Vol.337, p.139290-139290, Article 139290
• Main Authors: Rather, Sami-ullah, Sulaimon, Aliyu Adebayo, Shariff, Azmi M., Qasim, Ali, Bamufleh, Hisham Saeed, Alhumade, Hesham Abdulhamed, Saeed, Usman, Al-Alayah, Walid
• Format: Article
• Language: English
• Subjects: Animals; Carbon Dioxide; CO2 solubility; Density; Ionic Liquids; Moles; Solubility; Tetraethylammonium; Tetraethylammonium bromide; Tetramethylammonium bromide; Viscosity
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2023.139290

Carbon dioxide is a major greenhouse gas that is responsible for global warming and renders harmful effects on the atmosphere. The unconstrained release of CO2 into the atmosphere should be prevented and various techniques have been developed in this regard to capture CO2 using different solvents and other compounds. Ionic liquids are a suitable candidate to capture CO2 due to their better solubility behaviour. In this work, two ionic liquids namely tetramethylammonium bromide (TMAB) and tetraethylammonium bromide (TEAB) are employed experimentally to capture CO2 and investigate their solubility behaviour. The study is performed at the temperature values of 303 K, 313 K, and 323 K and the pressure values of 5, 10, 15, and 20 bar equivalent to 0.5, 1.0, 1.5, and 2.0 MPa respectively. The concentrations of both ionic liquid solutions are 2.5 wt%, 5.0 wt%, and 10.0 wt%. The solubility results are considered in terms of mol fraction which is the ratio of moles of CO2 captured per moles of ionic liquid. The density and viscosity values are also determined for both compounds at respective conditions. COSMO-RS is used to generate the sigma profile, sigma surface, and Henry's constant of the ions involved in the study. CO2 is found to be soluble in both ionic liquids, but TEAB showed better solubility behaviour as compared to TMAB. The solubility of CO2 is found to be increasing with the increase in pressure while it decreases with the increase in temperature. [Display omitted] •COSMO-RS study of ionic liquids properties.•CO2 solubility measurement in ionic liquids using high-pressure solubility cell.•Density measurement of ionic liquids in the temperature range of 303–323 K.•Viscosity measurement of ionic liquids in the pressure range of 5–20 bar.•High pressure CO2 solubility study in ionic liquids using Peng-Robinson EoS.