Methyl esters synthesis from Luffa cylindrica seeds oil using green copper oxide nanoparticle catalyst in membrane reactor

• Published in: Chemosphere (Oxford) 2023-10, Vol.338, p.139349-139349, Article 139349
• Main Authors: Alsaiari, Mabkhoot, Dawood, Sumreen, Ahmad, Mushtaq, Alsaiari, Raiedhah A., Rizk, Moustafa A., Asif, Saira
• Format: Article
• Language: English
• Subjects: Energy crop; Green Cu–O nanoparticle; LCSOB; Luffa cylindrica; Membrane; Non-edible seed oil
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2023.139349

This study investigates the potential role of Juglans sp. root extract-mediated copper oxide nanoparticles of Luffa cylindrica seed oil (LCSO) into methyl esters. The synthesized green nanoparticle was characterized by Energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), and Scanning electron microscopy (SEM) spectroscopies to find out the crystalline size (40 nm), surface morphology (rod shape), particle size (80–85 nm), and chemical composition (Cu = 80.25% & O = 19.75%), accordingly. The optimized protocol for the transesterification reaction was adjusted as oil to methanol molar ratio (1:7), copper oxide nano-catalyst concentration (0.2 wt %), and temperature (90 °C) corresponding to the maximum methyl esters yield of 95%. The synthesized methyl esters were characterized by GC-MS, 1H NMR, 13C NMR, and FT-IR studies to know and identify the chemical composition of newly synthesized Lufa biodiesel. The fuel properties of Luffa cylindrica seed oil biofuel were checked and compared with the American Biodiesel standards (ASTM) (D6751-10). Finally, it is commendable to use biodiesel made from wild, uncultivated, and non-edible Lufa cylindrica to promote and adopt a cleaner and sustainable energy method. The acceptance and implementation of the green energy method may result in favourable environmental effects, which in turn may lead to better societal and economic development. [Display omitted] •Green copper oxide nano-catalyst has been synthesized using Juglans regia root extract.•Structural analysis of the prepared nano-catalyst has been done successfully.•Biodiesel synthesis and optimization from LCSO have been performed.•CuO nano-catalyst displays high catalytic activity, stability, and cost efficiency.