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Synthesis of (Mg,Si)Al2O4 Spinel from Aluminum Dross

The spinel (Mg,Si)Al2O4 was synthesized from aluminum dross using an induction synthesis method. X‐ray diffraction analyses on products formed at different temperatures provided an understanding of the formation mechanism of the spinel. After removal of soluble components, the induction heating of t...

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Published in:	Journal of the American Ceramic Society 2004-03, Vol.87 (3), p.496-499
Main Authors:	Hashishin, Takeshi, Kodera, Yasuhiro, Yamamoto, Takeshi, Ohyanagi, Manshi, Munir, Zuhair A.
Format:	Article
Language:	English
Subjects:	aluminum Applied sciences Building materials. Ceramics. Glasses Chemical industry and chemicals Chemistry Elements and non-metal compounds (oxides, hydroxides, hydrides, sulfides, carbides, ...) Exact sciences and technology Inorganic chemistry and origins of life Preparations and properties Refractory products Special refractories spinels synthesis
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container_issue	3
container_start_page	496
container_title	Journal of the American Ceramic Society
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creator	Hashishin, Takeshi Kodera, Yasuhiro Yamamoto, Takeshi Ohyanagi, Manshi Munir, Zuhair A.
description	The spinel (Mg,Si)Al2O4 was synthesized from aluminum dross using an induction synthesis method. X‐ray diffraction analyses on products formed at different temperatures provided an understanding of the formation mechanism of the spinel. After removal of soluble components, the induction heating of the dross resulted first in the oxidation of some of the AlN component and the subsequent formation of the spinel by the following reaction: xSiO2+ (1−x)MgO + [1−(x/3)]Al2O3+ (2x/3)AlN = (Mg1−x,Six)Al2O4+ (x/3)N2(g).
doi_str_mv	10.1111/j.1551-2916.2004.00496.x
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X‐ray diffraction analyses on products formed at different temperatures provided an understanding of the formation mechanism of the spinel. After removal of soluble components, the induction heating of the dross resulted first in the oxidation of some of the AlN component and the subsequent formation of the spinel by the following reaction: xSiO2+ (1−x)MgO + [1−(x/3)]Al2O3+ (2x/3)AlN = (Mg1−x,Six)Al2O4+ (x/3)N2(g).</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/j.1551-2916.2004.00496.x</identifier><identifier>CODEN: JACTAW</identifier><language>eng</language><publisher>Westerville, Ohio: American Ceramics Society</publisher><subject>aluminum ; Applied sciences ; Building materials. Ceramics. 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Ceramics. 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subjects	aluminum Applied sciences Building materials. Ceramics. Glasses Chemical industry and chemicals Chemistry Elements and non-metal compounds (oxides, hydroxides, hydrides, sulfides, carbides, ...) Exact sciences and technology Inorganic chemistry and origins of life Preparations and properties Refractory products Special refractories spinels synthesis
title	Synthesis of (Mg,Si)Al2O4 Spinel from Aluminum Dross
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