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On the critical behavior of linear and nonlinear dielectric permittivity on approaching the critical consolute point

Results are presented of the dielectric permittivity /spl epsi/ and nonlinear dielectric effects (NDE) in binary mixtures on approaching the critical consolute point (CCP), focusing first on Piekara's findings [Phys. Rev. Vol.42, pp. 445-447, 1932, and C. R. Acad. Sci. Paris Vol. 203, pp. 1058-...

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Published in:IEEE transactions on dielectrics and electrical insulation 2002-02, Vol.9 (1), p.112-117
Main Authors: Drozd-Rzoska, A., Rzoska, S.J., Malike, P., Janik, P., Gorny, M., Ziolo, J.
Format: Article
Language:English
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Summary:Results are presented of the dielectric permittivity /spl epsi/ and nonlinear dielectric effects (NDE) in binary mixtures on approaching the critical consolute point (CCP), focusing first on Piekara's findings [Phys. Rev. Vol.42, pp. 445-447, 1932, and C. R. Acad. Sci. Paris Vol. 203, pp. 1058-1059, 1936]. The presented results cover changes in temperature and pressure. For NDE particular attention is given to complex liquid features of critical mixtures appearing in /spl epsi/ and NDE tests. The latter are presented for the stationary and dynamic (time-resolved NDE) behavior. New results for NDE in nitrobenzene, hexane mixture with the lowest measurement frequency ever applied and in benzonitrile-isooctane mixture for dielectric permittivity are also included. For the latter, the first test of the relation: d/spl epsi//dT /spl alpha/ (T - T/sub C/) /sup -/spl alpha// is shown.
ISSN:1070-9878
1558-4135
DOI:10.1109/94.983894