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Thermodynamic vaporization studies of the manganese oxide–yttria stabilized zirconia (YSZ) solid solution
Samples of the compositions (Zr 0.85Y 0.15) 1− x Mn x O 1.93−δ, 0.02⩽ x⩽0.25, were prepared and characterized by means of XRD and SEM/EDX analysis. The vaporization of manganese oxide from the samples with x ⩽0.18 was studied by Knudsen effusion mass spectrometry in the temperature range of 1539–185...
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| Published in: | Journal of the European Ceramic Society 2004-08, Vol.24 (9), p.2649-2656 |
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| Main Authors: | , , , |
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| cites | cdi_FETCH-LOGICAL-c445t-33b84eaac67ff4caf3227e7a1f43e6b4cb47ab12ac9eb91329b7c3ec90c544cf3 |
| container_end_page | 2656 |
| container_issue | 9 |
| container_start_page | 2649 |
| container_title | Journal of the European Ceramic Society |
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| creator | Matraszek, Aleksandra Miller, Miroslaw Singheiser, Lorenz Hilpert, Klaus |
| description | Samples of the compositions (Zr
0.85Y
0.15)
1−
x
Mn
x
O
1.93−δ, 0.02⩽
x⩽0.25, were prepared and characterized by means of XRD and SEM/EDX analysis. The vaporization of manganese oxide from the samples with
x ⩽0.18 was studied by Knudsen effusion mass spectrometry in the temperature range of 1539–1858 K. Partial pressures of gaseous Mn, MnO, and O
2 were determined over the samples investigated and thermodynamic activities of MnO in the samples evaluated at 1700 K. Chemical and phase compositions of the samples were determined after the vaporization measurements and the results obtained were correlated with the obtained values of the thermodynamic activity of MnO. The thermodynamic activities determined belong to the solubility range of manganese oxide in yttria stabilized zirconia. Moreover, thermodynamic data on the vaporisation of pure MnO(s) resulted. |
| doi_str_mv | 10.1016/j.jeurceramsoc.2003.09.015 |
| format | article |
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0.85Y
0.15)
1−
x
Mn
x
O
1.93−δ, 0.02⩽
x⩽0.25, were prepared and characterized by means of XRD and SEM/EDX analysis. The vaporization of manganese oxide from the samples with
x ⩽0.18 was studied by Knudsen effusion mass spectrometry in the temperature range of 1539–1858 K. Partial pressures of gaseous Mn, MnO, and O
2 were determined over the samples investigated and thermodynamic activities of MnO in the samples evaluated at 1700 K. Chemical and phase compositions of the samples were determined after the vaporization measurements and the results obtained were correlated with the obtained values of the thermodynamic activity of MnO. The thermodynamic activities determined belong to the solubility range of manganese oxide in yttria stabilized zirconia. Moreover, thermodynamic data on the vaporisation of pure MnO(s) resulted.</description><identifier>ISSN: 0955-2219</identifier><identifier>EISSN: 1873-619X</identifier><identifier>DOI: 10.1016/j.jeurceramsoc.2003.09.015</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Building materials. Ceramics. Glasses ; Ceramic industries ; Chemical industry and chemicals ; Chemical properties ; Condensed matter: structure, mechanical and thermal properties ; Energy ; Energy. Thermal use of fuels ; Equations of state, phase equilibria, and phase transitions ; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc ; Exact sciences and technology ; Fuel cells ; Liquid-vapor transitions ; Miscellaneous ; Physics ; Specific phase transitions ; Technical ceramics ; Vaporization ; ZrO 2</subject><ispartof>Journal of the European Ceramic Society, 2004-08, Vol.24 (9), p.2649-2656</ispartof><rights>2003 Elsevier Ltd</rights><rights>2004 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c445t-33b84eaac67ff4caf3227e7a1f43e6b4cb47ab12ac9eb91329b7c3ec90c544cf3</citedby><cites>FETCH-LOGICAL-c445t-33b84eaac67ff4caf3227e7a1f43e6b4cb47ab12ac9eb91329b7c3ec90c544cf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=15849196$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Matraszek, Aleksandra</creatorcontrib><creatorcontrib>Miller, Miroslaw</creatorcontrib><creatorcontrib>Singheiser, Lorenz</creatorcontrib><creatorcontrib>Hilpert, Klaus</creatorcontrib><title>Thermodynamic vaporization studies of the manganese oxide–yttria stabilized zirconia (YSZ) solid solution</title><title>Journal of the European Ceramic Society</title><description>Samples of the compositions (Zr
0.85Y
0.15)
1−
x
Mn
x
O
1.93−δ, 0.02⩽
x⩽0.25, were prepared and characterized by means of XRD and SEM/EDX analysis. The vaporization of manganese oxide from the samples with
x ⩽0.18 was studied by Knudsen effusion mass spectrometry in the temperature range of 1539–1858 K. Partial pressures of gaseous Mn, MnO, and O
2 were determined over the samples investigated and thermodynamic activities of MnO in the samples evaluated at 1700 K. Chemical and phase compositions of the samples were determined after the vaporization measurements and the results obtained were correlated with the obtained values of the thermodynamic activity of MnO. The thermodynamic activities determined belong to the solubility range of manganese oxide in yttria stabilized zirconia. Moreover, thermodynamic data on the vaporisation of pure MnO(s) resulted.</description><subject>Applied sciences</subject><subject>Building materials. Ceramics. Glasses</subject><subject>Ceramic industries</subject><subject>Chemical industry and chemicals</subject><subject>Chemical properties</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Energy</subject><subject>Energy. Thermal use of fuels</subject><subject>Equations of state, phase equilibria, and phase transitions</subject><subject>Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc</subject><subject>Exact sciences and technology</subject><subject>Fuel cells</subject><subject>Liquid-vapor transitions</subject><subject>Miscellaneous</subject><subject>Physics</subject><subject>Specific phase transitions</subject><subject>Technical ceramics</subject><subject>Vaporization</subject><subject>ZrO 2</subject><issn>0955-2219</issn><issn>1873-619X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNqNkcuK1UAQhhtR8Dj6DkFQdJHYt1zanYxXGHDhCOqmqVSqnT4m6TPdyeA5K9_BN_RJTDgDujybKii--uunfsYeC14ILqoX22JLc0SKMKSAheRcFdwUXJR32EY0tcorYb7cZRtuyjKXUpj77EFKW85FzY3ZsB-XVxSH0O1HGDxmN7AL0R9g8mHM0jR3nlIWXDZdUTbA-B1GSpSFn76jP79-76cpelg4aH3vD9RlBx8xjMvs2ddP355nKfS-W-u8Cj5k9xz0iR7d9jP2-e2by_P3-cXHdx_OX13kqHU55Uq1jSYArGrnNIJTUtZUg3BaUdVqbHUNrZCAhlojlDRtjYrQcCy1RqfO2NOj7i6G65nSZAefkPp-cR_mZGWjS2nK6hRQN8LwU0BZ86ZZwJdHEGNIKZKzu-gHiHsruF0Ts1v7f2J2TcxyY5fEluUnt1cgIfQuwog-_VMoG22EWW2_PnK0PPHGU7QJPY1InY-Ek-2CP-XcXyEht4U</recordid><startdate>20040801</startdate><enddate>20040801</enddate><creator>Matraszek, Aleksandra</creator><creator>Miller, Miroslaw</creator><creator>Singheiser, Lorenz</creator><creator>Hilpert, Klaus</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>7SP</scope><scope>7U5</scope><scope>L7M</scope><scope>7QQ</scope></search><sort><creationdate>20040801</creationdate><title>Thermodynamic vaporization studies of the manganese oxide–yttria stabilized zirconia (YSZ) solid solution</title><author>Matraszek, Aleksandra ; Miller, Miroslaw ; Singheiser, Lorenz ; Hilpert, Klaus</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c445t-33b84eaac67ff4caf3227e7a1f43e6b4cb47ab12ac9eb91329b7c3ec90c544cf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>Building materials. Ceramics. Glasses</topic><topic>Ceramic industries</topic><topic>Chemical industry and chemicals</topic><topic>Chemical properties</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Energy</topic><topic>Energy. Thermal use of fuels</topic><topic>Equations of state, phase equilibria, and phase transitions</topic><topic>Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc</topic><topic>Exact sciences and technology</topic><topic>Fuel cells</topic><topic>Liquid-vapor transitions</topic><topic>Miscellaneous</topic><topic>Physics</topic><topic>Specific phase transitions</topic><topic>Technical ceramics</topic><topic>Vaporization</topic><topic>ZrO 2</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Matraszek, Aleksandra</creatorcontrib><creatorcontrib>Miller, Miroslaw</creatorcontrib><creatorcontrib>Singheiser, Lorenz</creatorcontrib><creatorcontrib>Hilpert, Klaus</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Ceramic Abstracts</collection><jtitle>Journal of the European Ceramic Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Matraszek, Aleksandra</au><au>Miller, Miroslaw</au><au>Singheiser, Lorenz</au><au>Hilpert, Klaus</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermodynamic vaporization studies of the manganese oxide–yttria stabilized zirconia (YSZ) solid solution</atitle><jtitle>Journal of the European Ceramic Society</jtitle><date>2004-08-01</date><risdate>2004</risdate><volume>24</volume><issue>9</issue><spage>2649</spage><epage>2656</epage><pages>2649-2656</pages><issn>0955-2219</issn><eissn>1873-619X</eissn><abstract>Samples of the compositions (Zr
0.85Y
0.15)
1−
x
Mn
x
O
1.93−δ, 0.02⩽
x⩽0.25, were prepared and characterized by means of XRD and SEM/EDX analysis. The vaporization of manganese oxide from the samples with
x ⩽0.18 was studied by Knudsen effusion mass spectrometry in the temperature range of 1539–1858 K. Partial pressures of gaseous Mn, MnO, and O
2 were determined over the samples investigated and thermodynamic activities of MnO in the samples evaluated at 1700 K. Chemical and phase compositions of the samples were determined after the vaporization measurements and the results obtained were correlated with the obtained values of the thermodynamic activity of MnO. The thermodynamic activities determined belong to the solubility range of manganese oxide in yttria stabilized zirconia. Moreover, thermodynamic data on the vaporisation of pure MnO(s) resulted.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.jeurceramsoc.2003.09.015</doi><tpages>8</tpages></addata></record> |
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| ispartof | Journal of the European Ceramic Society, 2004-08, Vol.24 (9), p.2649-2656 |
| issn | 0955-2219 1873-619X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_28452956 |
| source | ScienceDirect Journals |
| subjects | Applied sciences Building materials. Ceramics. Glasses Ceramic industries Chemical industry and chemicals Chemical properties Condensed matter: structure, mechanical and thermal properties Energy Energy. Thermal use of fuels Equations of state, phase equilibria, and phase transitions Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc Exact sciences and technology Fuel cells Liquid-vapor transitions Miscellaneous Physics Specific phase transitions Technical ceramics Vaporization ZrO 2 |
| title | Thermodynamic vaporization studies of the manganese oxide–yttria stabilized zirconia (YSZ) solid solution |
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