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Crystal structures of the RCuPbSe3 (R = Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu) compounds

The crystal structures of the RCuPbSe3 (R = Gd, Th, Dy, Ho, Er, Tm, Yb and Lu) compounds (beta-BaLaCuSe3 structure type, space group Pnma, Pearson symbol oP24) were determined by means of X-ray powder diffraction: a = 1.0687(2) nm, b = 0.40858(5) nm, c = 1.3443(2) ran, R1 = 0.0856 (GdCuPbSe3); a = 1...

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Published in:Journal of alloys and compounds 2005-01, Vol.387 (1-2), p.160-164
Main Authors: GULAY, L. D, OLEKSEYUK, I. D
Format: Article
Language:English
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Summary:The crystal structures of the RCuPbSe3 (R = Gd, Th, Dy, Ho, Er, Tm, Yb and Lu) compounds (beta-BaLaCuSe3 structure type, space group Pnma, Pearson symbol oP24) were determined by means of X-ray powder diffraction: a = 1.0687(2) nm, b = 0.40858(5) nm, c = 1.3443(2) ran, R1 = 0.0856 (GdCuPbSe3); a = 1.0603(1) nm, b = 0.40680(3) nm, c = 1.3414(1) nm, R1 = 0.0870 (TbCuPbSe3); a = 1.05606(9) nm, b = 0.40594(3) nm, c = 1.34236(9) nm, R1 = 0.0833 (DyCuPbSe3); a = 1.0528(1) nm, b = 0.40516(5) urn, c = 1.3420(2) nm, R1 = 0.0912 (HoCuPbSe3); a = 1.04846(8) nm, b = 0.40424(3) run, c = 1.34143(7) nm, R1 = 0.0824 (ErCuPbSe3); a = 1.0447(1) nm, b = 0.40400(4) nm, c = 1.3423(1) nm, R1 = 0.0937 (TmCuPbSe3); a = 1.03988(5) nm, b = 0.40285(2) nm, c = 1.34089(5) nm, R1 = 0.0791 (YbCuPbSe3); a = 1.03857(6) urn, b = 0.40248(2) nm, c = 1.34056(6) nm, R1 = 0.0769 (LuCuPbSe3).
ISSN:0925-8388
1873-4669
DOI:10.1016/j.jallcom.2004.06.023