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Efficient Turn-On Zr Based Metal Organic Framework Fluorescent Sensor for Ultrafast Detection of Danofloxacin in Milk Samples
Metal organic framework, UiO-67 was synthesized by coordinating Zr(IV) with 4,4’-biphenyldicarboxylic acid (BPDC) ligand. Morphology and crystallinity of MOF was confirmed with FE-SEM and PXRD procedure. Danofloxacin (DANO), a veterinary fluoroquinolone antibiotic, was detected in milk by employing...
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| Published in: | Journal of fluorescence 2024-07, Vol.34 (4), p.1631-1642 |
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| Main Authors: | , , , , , |
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| cites | cdi_FETCH-LOGICAL-c419t-32a3f77b01edc962ce5396ff7292cdb2a90b3fbdf4014031e91f4dc9b1f64a03 |
| container_end_page | 1642 |
| container_issue | 4 |
| container_start_page | 1631 |
| container_title | Journal of fluorescence |
| container_volume | 34 |
| creator | Verma, Rajpal Dhingra, Gaurav Singh, Gurdeep Singh, Jaswinder Dureja, Nidhi Malik, Ashok Kumar |
| description | Metal organic framework, UiO-67 was synthesized by coordinating Zr(IV) with 4,4’-biphenyldicarboxylic acid (BPDC) ligand. Morphology and crystallinity of MOF was confirmed with FE-SEM and PXRD procedure. Danofloxacin (DANO), a veterinary fluoroquinolone antibiotic, was detected in milk by employing UiO-67 as “turn-on” fluorescent sensor. Original photoluminescent (PL) efficiency of UiO-67 sensor was enhanced on its electronic interaction with DANO molecule. Significant PL efficiency enhancement, lower detection limit 0.49 ng/mL (1.37 nM), swift detection (time |
| doi_str_mv | 10.1007/s10895-023-03379-w |
| format | article |
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2
= 0.9988) indicated extraordinary sensitivity of developed UiO-67 sensor for DANO. Selectivity and performance of sensor was unaltered in presence of interfering species and detection results were obtained under permissible variation limits. Method applied successfully for ultra-trace detection of DANO residues in milk samples.
Graphical Abstract</description><identifier>ISSN: 1053-0509</identifier><identifier>ISSN: 1573-4994</identifier><identifier>EISSN: 1573-4994</identifier><identifier>DOI: 10.1007/s10895-023-03379-w</identifier><identifier>PMID: 37578675</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Analytical Chemistry ; Animals ; Anti-Bacterial Agents - analysis ; Biochemistry ; Biological and Medical Physics ; Biomedical and Life Sciences ; Biomedicine ; Biophysics ; Biotechnology ; Fluorescence ; Fluorescent Dyes - chemistry ; Fluoroquinolones - analysis ; Limit of Detection ; Metal-organic frameworks ; Metal-Organic Frameworks - chemistry ; Milk - chemistry ; Nitrofurans - analysis ; Photoluminescence ; Spectrometry, Fluorescence ; Zirconium ; Zirconium - chemistry</subject><ispartof>Journal of fluorescence, 2024-07, Vol.34 (4), p.1631-1642</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>2023. The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c419t-32a3f77b01edc962ce5396ff7292cdb2a90b3fbdf4014031e91f4dc9b1f64a03</citedby><cites>FETCH-LOGICAL-c419t-32a3f77b01edc962ce5396ff7292cdb2a90b3fbdf4014031e91f4dc9b1f64a03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37578675$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Verma, Rajpal</creatorcontrib><creatorcontrib>Dhingra, Gaurav</creatorcontrib><creatorcontrib>Singh, Gurdeep</creatorcontrib><creatorcontrib>Singh, Jaswinder</creatorcontrib><creatorcontrib>Dureja, Nidhi</creatorcontrib><creatorcontrib>Malik, Ashok Kumar</creatorcontrib><title>Efficient Turn-On Zr Based Metal Organic Framework Fluorescent Sensor for Ultrafast Detection of Danofloxacin in Milk Samples</title><title>Journal of fluorescence</title><addtitle>J Fluoresc</addtitle><addtitle>J Fluoresc</addtitle><description>Metal organic framework, UiO-67 was synthesized by coordinating Zr(IV) with 4,4’-biphenyldicarboxylic acid (BPDC) ligand. Morphology and crystallinity of MOF was confirmed with FE-SEM and PXRD procedure. Danofloxacin (DANO), a veterinary fluoroquinolone antibiotic, was detected in milk by employing UiO-67 as “turn-on” fluorescent sensor. Original photoluminescent (PL) efficiency of UiO-67 sensor was enhanced on its electronic interaction with DANO molecule. Significant PL efficiency enhancement, lower detection limit 0.49 ng/mL (1.37 nM), swift detection (time < 1 min), and excellent linear correlation (R
2
= 0.9988) indicated extraordinary sensitivity of developed UiO-67 sensor for DANO. Selectivity and performance of sensor was unaltered in presence of interfering species and detection results were obtained under permissible variation limits. Method applied successfully for ultra-trace detection of DANO residues in milk samples.
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Morphology and crystallinity of MOF was confirmed with FE-SEM and PXRD procedure. Danofloxacin (DANO), a veterinary fluoroquinolone antibiotic, was detected in milk by employing UiO-67 as “turn-on” fluorescent sensor. Original photoluminescent (PL) efficiency of UiO-67 sensor was enhanced on its electronic interaction with DANO molecule. Significant PL efficiency enhancement, lower detection limit 0.49 ng/mL (1.37 nM), swift detection (time < 1 min), and excellent linear correlation (R
2
= 0.9988) indicated extraordinary sensitivity of developed UiO-67 sensor for DANO. Selectivity and performance of sensor was unaltered in presence of interfering species and detection results were obtained under permissible variation limits. Method applied successfully for ultra-trace detection of DANO residues in milk samples.
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| subjects | Analytical Chemistry Animals Anti-Bacterial Agents - analysis Biochemistry Biological and Medical Physics Biomedical and Life Sciences Biomedicine Biophysics Biotechnology Fluorescence Fluorescent Dyes - chemistry Fluoroquinolones - analysis Limit of Detection Metal-organic frameworks Metal-Organic Frameworks - chemistry Milk - chemistry Nitrofurans - analysis Photoluminescence Spectrometry, Fluorescence Zirconium Zirconium - chemistry |
| title | Efficient Turn-On Zr Based Metal Organic Framework Fluorescent Sensor for Ultrafast Detection of Danofloxacin in Milk Samples |
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