Grafting studies onto cellulose by atom-transfer radical polymerization

• Published in: Polymer international 2005-02, Vol.54 (2), p.342-347
• Main Authors: Coskun, Mehmet, Temüz, Mehmet Mürşit
• Format: Article
• Language: English
• Subjects: Applied sciences; atom transfer radical polymerization; cellulose; Cellulose and derivatives; Exact sciences and technology; graft copolymer; Natural polymers; Physicochemistry of polymers
• ISSN: 0959-8103; 1097-0126
• DOI: 10.1002/pi.1684

Styrene (Sty), methyl methacrylate (MMA), methacrylamide (MAm) and acrylomorpholine (AcM) were grafted onto powder cellulose by atom‐transfer radical polymerization. Cellulose chloroacetate (Cell‐ClAc), as a macro‐initiator, was first prepared by the reaction of chloroacetyl chloride with primary alcoholic OH groups on powder cellulose. CuBr and 1,2‐dipiperidinoethane were used as a transition‐metal compound and as a ligand, respectively. These reactions were monitored by FT‐IR and weight increase in Cell‐ClAc. In case of styrene, although some weight increase occurred, no evidence of grafting could be observed in the FT‐IR spectrum, while there were strong evidence of grafting with MMA, MAm and AcM. Cell‐graft‐MAm, Cell‐graft‐AcM and Cell‐graft‐MMA showed new carbonyl bands at 1665, 1640 and 1735 cm−1, respectively. Dye‐uptake and dye‐absorption properties of cellulose, for alizarin yellow (basic dye) and bromocresol green (acidic dye), and its moisture‐ and water‐uptake capacities improved with the grafting, but some decrease was observed in thermal stability. Copyright © 2004 Society of Chemical Industry