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Reactivity of Cyclic (Alkyl)(amino)germylene towards Copper(I) and Gold(I) Complexes
The reactions of cyclic (alkyl)(amino)germylenes (CAAGe) with copper(I) and gold(I) complexes were investigated. CAAGe ( 1 ) reacts with CuBr(SMe 2 ) leading to a tetrameric germylene complex [CAAGeCuBr] 4 ( 2 ), whereas CAAGe ( 3 ) undergoes Au−Cl bond insertion with LAuCl (L=phosphine or N‐heteroc...
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| Published in: | Chemistry, an Asian journal an Asian journal, 2023-10, Vol.18 (19), p.e202300634-e202300634 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c340t-526c9ec9c20039195515952752c499d4121e95d4ec32b357783406b9c34327773 |
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| cites | cdi_FETCH-LOGICAL-c340t-526c9ec9c20039195515952752c499d4121e95d4ec32b357783406b9c34327773 |
| container_end_page | e202300634 |
| container_issue | 19 |
| container_start_page | e202300634 |
| container_title | Chemistry, an Asian journal |
| container_volume | 18 |
| creator | Feng, Zhongtao Wang, Liliang Mohammed, Sharifah Nadhirah Binte Shaik Rao, Bin Kinjo, Rei |
| description | The reactions of cyclic (alkyl)(amino)germylenes (CAAGe) with copper(I) and gold(I) complexes were investigated. CAAGe (
1
) reacts with CuBr(SMe
2
) leading to a tetrameric germylene complex [CAAGeCuBr]
4
(
2
), whereas CAAGe (
3
) undergoes Au−Cl bond insertion with LAuCl (L=phosphine or N‐heterocyclic carbene) to afford germanium gold(I) complexes (
5
and
6
). Chlorine abstraction of
6
gives the cationic germylene gold(I) complex
7
. |
| doi_str_mv | 10.1002/asia.202300634 |
| format | article |
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1
) reacts with CuBr(SMe
2
) leading to a tetrameric germylene complex [CAAGeCuBr]
4
(
2
), whereas CAAGe (
3
) undergoes Au−Cl bond insertion with LAuCl (L=phosphine or N‐heterocyclic carbene) to afford germanium gold(I) complexes (
5
and
6
). Chlorine abstraction of
6
gives the cationic germylene gold(I) complex
7
.</description><identifier>ISSN: 1861-4728</identifier><identifier>EISSN: 1861-471X</identifier><identifier>DOI: 10.1002/asia.202300634</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Chemistry ; Chlorine ; Copper ; Germanium ; Gold ; Phosphines</subject><ispartof>Chemistry, an Asian journal, 2023-10, Vol.18 (19), p.e202300634-e202300634</ispartof><rights>2023 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c340t-526c9ec9c20039195515952752c499d4121e95d4ec32b357783406b9c34327773</citedby><cites>FETCH-LOGICAL-c340t-526c9ec9c20039195515952752c499d4121e95d4ec32b357783406b9c34327773</cites><orcidid>0000-0002-4425-3937</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Feng, Zhongtao</creatorcontrib><creatorcontrib>Wang, Liliang</creatorcontrib><creatorcontrib>Mohammed, Sharifah Nadhirah Binte Shaik</creatorcontrib><creatorcontrib>Rao, Bin</creatorcontrib><creatorcontrib>Kinjo, Rei</creatorcontrib><title>Reactivity of Cyclic (Alkyl)(amino)germylene towards Copper(I) and Gold(I) Complexes</title><title>Chemistry, an Asian journal</title><description>The reactions of cyclic (alkyl)(amino)germylenes (CAAGe) with copper(I) and gold(I) complexes were investigated. CAAGe (
1
) reacts with CuBr(SMe
2
) leading to a tetrameric germylene complex [CAAGeCuBr]
4
(
2
), whereas CAAGe (
3
) undergoes Au−Cl bond insertion with LAuCl (L=phosphine or N‐heterocyclic carbene) to afford germanium gold(I) complexes (
5
and
6
). Chlorine abstraction of
6
gives the cationic germylene gold(I) complex
7
.</description><subject>Chemistry</subject><subject>Chlorine</subject><subject>Copper</subject><subject>Germanium</subject><subject>Gold</subject><subject>Phosphines</subject><issn>1861-4728</issn><issn>1861-471X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpdkMFLwzAUh4MoOKdXzwUv3aEzeWma5DiKzsFAkAneSpZm0pk2NWnV_vd2THbw9H6H7_fe40PoluA5wRjuVajUHDBQjDOanqEJERlJUk7ezk8ZxCW6CmGPMQMsxQRtXozSXfVVdUPkdlE-aFvpKF7Yj8HOYlVXjZu9G18P1jQm6ty38mWIcte2xserWaSaMlo6Wx5y7urWmh8TrtHFTtlgbv7mFL0-Pmzyp2T9vFzli3WiaYq7hEGmpdFSA8ZUEskYYZIBZ6BTKcuUADGSlanRFLaUcS7GWraVY5sC55xOUXzc23r32ZvQFXUVtLFWNcb1oQDBhBQ8E9mI3v1D9673zfjdSHFIQY6nR2p-pLR3IXizK1pf1coPBcHFQXJxkFycJNNf5GJsEQ</recordid><startdate>20231004</startdate><enddate>20231004</enddate><creator>Feng, Zhongtao</creator><creator>Wang, Liliang</creator><creator>Mohammed, Sharifah Nadhirah Binte Shaik</creator><creator>Rao, Bin</creator><creator>Kinjo, Rei</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-4425-3937</orcidid></search><sort><creationdate>20231004</creationdate><title>Reactivity of Cyclic (Alkyl)(amino)germylene towards Copper(I) and Gold(I) Complexes</title><author>Feng, Zhongtao ; Wang, Liliang ; Mohammed, Sharifah Nadhirah Binte Shaik ; Rao, Bin ; Kinjo, Rei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c340t-526c9ec9c20039195515952752c499d4121e95d4ec32b357783406b9c34327773</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Chemistry</topic><topic>Chlorine</topic><topic>Copper</topic><topic>Germanium</topic><topic>Gold</topic><topic>Phosphines</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Feng, Zhongtao</creatorcontrib><creatorcontrib>Wang, Liliang</creatorcontrib><creatorcontrib>Mohammed, Sharifah Nadhirah Binte Shaik</creatorcontrib><creatorcontrib>Rao, Bin</creatorcontrib><creatorcontrib>Kinjo, Rei</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry, an Asian journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Feng, Zhongtao</au><au>Wang, Liliang</au><au>Mohammed, Sharifah Nadhirah Binte Shaik</au><au>Rao, Bin</au><au>Kinjo, Rei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reactivity of Cyclic (Alkyl)(amino)germylene towards Copper(I) and Gold(I) Complexes</atitle><jtitle>Chemistry, an Asian journal</jtitle><date>2023-10-04</date><risdate>2023</risdate><volume>18</volume><issue>19</issue><spage>e202300634</spage><epage>e202300634</epage><pages>e202300634-e202300634</pages><issn>1861-4728</issn><eissn>1861-471X</eissn><abstract>The reactions of cyclic (alkyl)(amino)germylenes (CAAGe) with copper(I) and gold(I) complexes were investigated. CAAGe (
1
) reacts with CuBr(SMe
2
) leading to a tetrameric germylene complex [CAAGeCuBr]
4
(
2
), whereas CAAGe (
3
) undergoes Au−Cl bond insertion with LAuCl (L=phosphine or N‐heterocyclic carbene) to afford germanium gold(I) complexes (
5
and
6
). Chlorine abstraction of
6
gives the cationic germylene gold(I) complex
7
.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/asia.202300634</doi><orcidid>https://orcid.org/0000-0002-4425-3937</orcidid><oa>free_for_read</oa></addata></record> |
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| identifier | ISSN: 1861-4728 |
| ispartof | Chemistry, an Asian journal, 2023-10, Vol.18 (19), p.e202300634-e202300634 |
| issn | 1861-4728 1861-471X |
| language | eng |
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| source | Wiley:Jisc Collections:Wiley Read and Publish Open Access 2024-2025 (reading list) |
| subjects | Chemistry Chlorine Copper Germanium Gold Phosphines |
| title | Reactivity of Cyclic (Alkyl)(amino)germylene towards Copper(I) and Gold(I) Complexes |
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