Ammonium Sulfite Slurry from Ammonia-Based Desulfurization Activates Water-Soluble Humic Substances from Lignite: Performance, Application, and Mechanism

• Published in: Journal of agricultural and food chemistry 2023-09, Vol.71 (37), p.13633-13644
• Main Authors: Zhao, Shanshan, Chen, Denglun, Yao, Yuanyuan, Liu, Chenghao, Gao, Bin, Liu, Yan, Liu, Jiahui, Wang, Songyuan, Gao, Ni, Yang, Mingchuan, Shi, Guifang, Zhang, Shugang, Xie, Jiazhuo, Yang, Yuechao
• Format: Article
• Language: English
• Subjects: Agricultural and Environmental Chemistry
• ISSN: 0021-8561; 1520-5118
• DOI: 10.1021/acs.jafc.3c02558

Both ammonium sulfite slurry (ASS) from ammonia-based desulfurization and lignite are waste materials with low value. In this work, an innovative method was developed by applying ASS in lignite activation to produce water-soluble humic substances (WHSs) with a high bioactivity and economic value. The optimal activation method was to mix lignite and ASS at a 4:1-liquid–solid ratio by vortex blender and then oscillate it for 30 min at 25 °C. Compared with that of the unactivated lignite (UAL), the yield of WHSs from activated lignite (AL) increased by 42.72%. WHSs from AL consisted of a large number of aliphatic carbons with low molecular weight and functional groups such as amides, amines, sulfonic acid groups, C–O, and so forth. Moreover, WHSs from AL at lower concentrations (2 mg/L) has a more obvious root-elongation-promoting effect than WHSs from UAL (10 mg/L). Activation experiment with the lignite-related model compounds revealed that ASS caused the breakage of Caliph–O, Caliph–Caliph, and Carom–Caliph linkages between aromatic rings. These findings provide a theoretical basis for the development of green and sustainable technologies for the beneficial reuse of ASS and lignite in agriculture.