Two-phase production of cyclohexene and cyclooctene oxides in water as an approach to pollution prevention

• Published in: Journal of chemical technology and biotechnology (1986) 2005-03, Vol.80 (3), p.273-280
• Main Author: Shu, Hung-Yee
• Format: Article
• Language: English
• Subjects: Applied sciences; Biotechnology; Chemistry; cyclohexene; cyclooctene; droplet column reactor; epoxidation; Exact sciences and technology; Global environmental pollution; Kinetics and mechanisms; Organic chemistry; Oxone; Pollution; pollution prevention; Reactivity and mechanisms
• ISSN: 0268-2575; 1097-4660
• DOI: 10.1002/jctb.1184

Liquid–liquid two‐phase epoxidation from cyclohexene and cyclooctene in aqueous potassium peroxymonosulfate (commercially available as Oxone®) solution was studied as an application in pollution prevention. To avoid potential emissions of volatile organic compounds an aqueous solution was employed to replace the usual chlorinated solvents used in epoxide production. A droplet column reactor and stirred tank reactor were used to investigate two‐phase synthesis of epoxide. An aqueous Oxone® solution was used to oxidize a dispersion of alkene droplets and form epoxide. The study of aqueous epoxidation in both reactors showed that the epoxidation of alkenes can be represented as a first order reaction with respect to alkene. The salting out effect of Oxone® concentration was studied in both reactors and found to be very similar at optimal conditions. In comparing the two reactors, it was found that the droplet column reactor produces larger quantities of product per unit reactor volume for the same reaction time. The objective of this study is to provide an alternative reactor design and synthesis route that can meet pollution prevention goals. Copyright © 2004 Society of Chemical Industry