Thermal properties of Er(Co 1− x Si x ) 2 compounds

• Published in: Journal of alloys and compounds 2005-05, Vol.394 (1), p.96-100
• Main Authors: Vasylyev, D., Prokleška, J., Šebek, J., Sechovský, V.
• Format: Article
• Language: English
• Subjects: Condensed matter: electronic structure, electrical, magnetic, and optical properties; Condensed matter: structure, mechanical and thermal properties; ErCo 2; Exact sciences and technology; Magnetic phase transition; Magnetic properties and materials; Magnetocaloric effect; Physics; Specific heat; Spin arrangements in magnetically ordered materials (including neutron and spin-polarized electron studies, synchrotron-source x-ray scattering, etc.); Thermal conductivity; Thermal properties of condensed matter
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2004.11.003

Results of specific heat and thermal conductivity measurements performed on the ErCo 2 and Er(Co 0.95Si 0.05) 2 compounds are presented with the emphasis on the phenomena associated with the magnetic ordering transition and their evolution with varying the chemical composition and the applied magnetic field. From specific heat data the magnetocaloric effect (MCE) in a wide temperature interval around the transition has been evaluated for several values of magnetic field. The maximum determined size of MCE makes these materials potentially applicable in magnetic cooling. The sensitivity of the Curie temperature ( T C) to the Si substitution for Co without any dramatic suppression of MCE offers an effective way for tuning the temperature range available for magnetocaloric applications. The pronounced sharp thermal-conductivity anomaly in ErCo 2 in the vicinity of T C is nearly suppressed in Er(Co 0.95Si 0.05) 2. The role of spin fluctuations in these phenomena is discussed.