Rational Design of Porous Ionic Liquids for Coupling Natural Gas Purification with Waste Gas Conversion

• Published in: Angewandte Chemie International Edition 2023-11, Vol.62 (46), p.e202310741-n/a
• Main Authors: Ning, Hailong, Shi, Mingzhen, Yang, Qian, Huang, Jingwei, Zhang, Xiaomin, Wu, Youting, Jie, Kecheng
• Format: Article
• Language: English
• Subjects: Active sites; Amines; Antihypertensives; Captopril; Carbon dioxide; Catalysis; Catalytic Conversion; Catalytic converters; CH4 Purification; Chemical synthesis; Continuous flow; Density functional theory; Exhaust gases; Flow separation; H2S Adsorption; Hydrogen sulfide; Impurities; Ionic Liquids; Methane; Molecular dynamics; Monte Carlo simulation; Nanocrystals; Natural gas; Pores; Porous Liquids; Purification; Trace impurities
• ISSN: 1433-7851; 1521-3773
• DOI: 10.1002/anie.202310741

Removal of trace impurities for natural gas purification coupled with waste gas conversion is highly desired in industry. We here report a type of porous ionic liquids (PILs) that can realize the continuous flow separation of CH4/CO2/H2S and the conversion of the captured H2S to useful products. The PILs are synthesized through a step‐by‐step surface modification of ionic liquids (ILs) onto UiO‐66‐OH nanocrystals. The introduction of free tertiary amine groups on the nanocrystal surface endows these PILs with an exceptional ability to enrich H2S from CO2 and CH4 with impressive selectivity, while the permanent pores of UiO‐66‐OH act as containers to store an exceptionally higher amount of the selectively captured H2S than the corresponding nonporous ILs. Simultaneously, the tertiary amines as dual functional moieties offer effective catalytic sites for the conversion of the H2S stored in PILs into 3‐mercaptoisobutyric acid, a key intermediate required for the synthesis of Captopril (an antihypertensive drug). Molecular dynamics, density functional theory calculations and Grand Canonical Monte Carlo simulations help understand both the mechanisms of separation and catalysis performance, confirming that the tertiary amines as well as the permanent pores in UiO‐66‐OH play vital roles in the whole procedure. Removal of trace impurities for natural gas purification coupled with waste gas conversion is highly desired in industry. We for the first time report a type of porous ionic liquids that can realize the continuous flow separation of CH4/CO2/H2S and the conversion of the captured H2S to useful products.