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Characterization and Comparative Study of Energy Efficient Mechanochemically Induced NASICON Sodium Solid Electrolyte Synthesis
In recent years, there is growing interest in solid‐state electrolytes due to their many promising properties, making them key to the future of battery technology. This future depends among other things on easy processing technologies for the solid electrolyte. The sodium superionic conductor (NASIC...
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Published in: | ChemSusChem 2024-01, Vol.17 (2), p.e202300809-n/a |
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description | In recent years, there is growing interest in solid‐state electrolytes due to their many promising properties, making them key to the future of battery technology. This future depends among other things on easy processing technologies for the solid electrolyte. The sodium superionic conductor (NASICON) Na3Zr2Si2PO12 is a promising sodium solid electrolyte; however, reported methods of synthesis are time consuming. To this effect, attempt was made to develop a simple time efficient alternative processing route. Firstly, a comparative study between a new method and commonly reported methods was carried out to gain a clear insight into the mechanism of formation of sodium superionic conductors (NASICON). It was observed that through a careful selection of precursors, and the use of high‐energy milling (HEM) the NASICON conversion process was enhanced and optimized, this reduces the processing time and required energy, opening up a new alternative route for synthesis. The obtained solid electrolyte was stable during Na cycling vs. Na‐metal at 1 mA cm−1, and a room temperature conductivity of 1.8 mS cm−1 was attained.
The study investigates the efficiency of high energy milling (HEM) in simplifying the processing of Sodium NASICON solid electrolyte, optimised the method and studied the stability of the HEM SE against Na metal and NMO active material. |
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The study investigates the efficiency of high energy milling (HEM) in simplifying the processing of Sodium NASICON solid electrolyte, optimised the method and studied the stability of the HEM SE against Na metal and NMO active material.</description><identifier>ISSN: 1864-5631</identifier><identifier>EISSN: 1864-564X</identifier><identifier>DOI: 10.1002/cssc.202300809</identifier><identifier>PMID: 37721363</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Ball milling ; Comparative studies ; Conductors ; Electrolytes ; Molten salt electrolytes ; NASICON ; processing ; Room temperature ; Sodium ; Solid electrolytes ; Synthesis ; Thermal conductivity</subject><ispartof>ChemSusChem, 2024-01, Vol.17 (2), p.e202300809-n/a</ispartof><rights>2023 The Authors. ChemSusChem published by Wiley-VCH GmbH</rights><rights>2023 The Authors. ChemSusChem published by Wiley-VCH GmbH.</rights><rights>2023. This article is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4679-677f7b60ece1e7478e6d9050554a5bed35f4a25a04c774d5b1d19027fc91a6a43</citedby><cites>FETCH-LOGICAL-c4679-677f7b60ece1e7478e6d9050554a5bed35f4a25a04c774d5b1d19027fc91a6a43</cites><orcidid>0000-0003-0091-8463 ; 0000-0001-5087-0272 ; 0000-0002-5134-7130</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37721363$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Gebi, Asma'u I.</creatorcontrib><creatorcontrib>Dolokto, Oleksandr</creatorcontrib><creatorcontrib>Mereacre, Liuda</creatorcontrib><creatorcontrib>Geckle, Udo</creatorcontrib><creatorcontrib>Radinger, Hannes</creatorcontrib><creatorcontrib>Knapp, Michael</creatorcontrib><creatorcontrib>Ehrenberg, Helmut</creatorcontrib><title>Characterization and Comparative Study of Energy Efficient Mechanochemically Induced NASICON Sodium Solid Electrolyte Synthesis</title><title>ChemSusChem</title><addtitle>ChemSusChem</addtitle><description>In recent years, there is growing interest in solid‐state electrolytes due to their many promising properties, making them key to the future of battery technology. This future depends among other things on easy processing technologies for the solid electrolyte. The sodium superionic conductor (NASICON) Na3Zr2Si2PO12 is a promising sodium solid electrolyte; however, reported methods of synthesis are time consuming. To this effect, attempt was made to develop a simple time efficient alternative processing route. Firstly, a comparative study between a new method and commonly reported methods was carried out to gain a clear insight into the mechanism of formation of sodium superionic conductors (NASICON). It was observed that through a careful selection of precursors, and the use of high‐energy milling (HEM) the NASICON conversion process was enhanced and optimized, this reduces the processing time and required energy, opening up a new alternative route for synthesis. The obtained solid electrolyte was stable during Na cycling vs. Na‐metal at 1 mA cm−1, and a room temperature conductivity of 1.8 mS cm−1 was attained.
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subjects | Ball milling Comparative studies Conductors Electrolytes Molten salt electrolytes NASICON processing Room temperature Sodium Solid electrolytes Synthesis Thermal conductivity |
title | Characterization and Comparative Study of Energy Efficient Mechanochemically Induced NASICON Sodium Solid Electrolyte Synthesis |
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