Highly efficient near-infrared solid solution phosphors with excellent thermal stability and tunable spectra for pc-LED light sources toward NIR spectroscopy applications

• Published in: Physical chemistry chemical physics : PCCP 2023-10, Vol.25 (38), p.25985-25992
• Main Authors: Lang, Tianchun, Zhao, Qunyang, Jing, Xiaolong, Guan, Gaoxuanyu, Fang, Shuangqiang, Qiang, Qinping, Peng, Lingling, Han, Tao, Yakovlev, Alexey N, Liu, Bitao
• Format: Article
• Language: English
• Subjects: Light emitting diodes; Light sources; Near infrared radiation; Phosphors; Photoluminescence; Photosynthesis; Red shift; Solid solutions; Spectrum analysis; Thermal stability; Trivalent chromium
• ISSN: 1463-9076; 1463-9084
• DOI: 10.1039/d3cp03634k

Near-infrared (NIR) luminescent materials have attracted wide research interest due to their unique photophysical properties for designing NIR light-emitting diodes (NIR LEDs). Here, a series of Cr 3+ -activated NIR-emitting solid solution phosphors, Gd 1− x Lu x (Al 1− x Sc x ) 3 (BO 3 ) 4 :0.01Cr 3+ (GLASB:Cr 3+ ) ( x = 0 to 0.5), are successfully synthesized via a cosubstitution approach. The GLASB:Cr 3+ phosphors reveal extraordinary optical performance with a desirable high IQE of 93.6%, considerable broadened FWHM (from 128 nm to 196 nm) and redshift of 119 nm (747 → 866 nm) as the amount of [Lu 3+ -Sc 3+ ] ion doping increases. Moreover, their photoluminescent thermal stability is substantially improved, maintaining 105.7% of the initial integral intensity up to 150 °C, namely zero-thermal-quenching. The NIR pc-LED fabricated using the GLASB:Cr 3+ phosphor generates an NIR output power of 46 mW and an electro-optical efficiency of 37% at a 120 mA input current. Finally, the characteristic NIR emission of this phosphor can not only be utilized in the fields of night-vision technology and biometric identification, but also exhibits a perfect match with the absorption of the bacteriochlorophyll (BChl) and light-harvesting protein (LHP) of photosynthetic bacteria (PSB), presenting a high application prospect for improving PSB photosynthesis. We develop NIR-emitting Gd 1− x Lu x (Al 1− x Sc x ) 3 (BO 3 ) 4 :0.01Cr 3+ phosphors with a high IQE of 93.6%, broadened FWHM of 196 nm and zero-thermal-quenching. These phosphors can be used in the field of supplementary lighting of PSB photosynthesis.