Gold(I)-Organic Frameworks as Catalysts for Carboxylation of Alkynes with CO2

Construction of gold-based metal–organic frameworks (Au-MOFs) would bring the merits of gold chemistry into MOFs. However, it still remains challenging because gold cations are easily reduced to metallic gold under solvothermal conditions. Herein, we present the first example of Au-MOFs prepared fro...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2023-10, Vol.145 (41), p.22720-22727
Main Authors: Wei, Rong-Jia, Xie, Mo, Xia, Ri-Qin, Chen, Jun, Hu, Hua-Juan, Ning, Guo-Hong, Li, Dan
Format: Article
Language:English
Online Access:Get full text
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Summary:Construction of gold-based metal–organic frameworks (Au-MOFs) would bring the merits of gold chemistry into MOFs. However, it still remains challenging because gold cations are easily reduced to metallic gold under solvothermal conditions. Herein, we present the first example of Au-MOFs prepared from the networking of cyclic trinuclear gold­(I) complexes by formal transimination reaction in a rapid (
ISSN:0002-7863
1520-5126
DOI:10.1021/jacs.3c08262