A Modular and Convergent Synthetic Route to Supramolecular Cyclic Dimers Based on Amidinium‐Carboxylate Interactions

We describe herein the optimized design and modular synthetic approach towards supramolecularly programmed monomers that can form discrete macrocyclic species of controllable size and shape through amidinium‐carboxylate interactions in apolar and polar media. A versatile synthetic approach towards s...

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Bibliographic Details
Published in:Chemistry : a European journal 2023-11, Vol.29 (64), p.e202302279-n/a
Main Authors: López‐Martín, Isabel, Veiga‐Herrero, Jacobo, Aparicio, Fátima, González‐Rodríguez, David
Format: Article
Language:English
Subjects:
amidinium-carboxylate Interactions
Chemistry
Controllability
Design optimization
hydrogen-bonding
Modular design
Monomers
supramolecular cyclizations
π-conjugated macrocycles
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Summary:We describe herein the optimized design and modular synthetic approach towards supramolecularly programmed monomers that can form discrete macrocyclic species of controllable size and shape through amidinium‐carboxylate interactions in apolar and polar media. A versatile synthetic approach towards supramolecularly programmed monomers that can form discrete macrocyclic species of controllable size and shape through amidinium‐carboxylate interactions in both apolar and polar media is described.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.202302279