Rheological and mechanical properties of percolated cyanate ester nanocomposites

The rheological properties and mechanical properties of percolated cyanate ester monomer/layered silicate mixtures are reported. A number of different cation exchanged montmorillonites were examined in an effort to achieve maximal montmorillonite delamination. The dispersion throughout the cyanate e...

Full description

Saved in:
Bibliographic Details
Published in:Polymer (Guilford) 2005-09, Vol.46 (19), p.8011-8017
Main Authors: Wooster, Tim J., Abrol, Simmi, MacFarlane, Douglas R.
Format: Article
Language:English
Subjects:
Applied sciences
Composites
Cyanate ester
Exact sciences and technology
Forms of application and semi-finished materials
Montmorillonite
Polymer industry, paints, wood
Rheology
Technology of polymers
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c432t-931b711a1364d34a370e9b53eff9f83e9810a89df54e1afd4e0bb3a1345d3c5b3
cites cdi_FETCH-LOGICAL-c432t-931b711a1364d34a370e9b53eff9f83e9810a89df54e1afd4e0bb3a1345d3c5b3
container_end_page 8017
container_issue 19
container_start_page 8011
container_title Polymer (Guilford)
container_volume 46
creator Wooster, Tim J.
Abrol, Simmi
MacFarlane, Douglas R.
description The rheological properties and mechanical properties of percolated cyanate ester monomer/layered silicate mixtures are reported. A number of different cation exchanged montmorillonites were examined in an effort to achieve maximal montmorillonite delamination. The dispersion throughout the cyanate ester of a montmorillonite with phenylated ammonium cations (2MBHT MMT) results in the formation of a percolated network. The rheology of this percolated network undergoes a viscous liquid to elastic solid transition at 4wt% montmorillonite. The percolation of the montmorillonite in the cyanate ester results in a significant improvement in crack resistance (80%) without a sacrifice of flexural strength.
doi_str_mv 10.1016/j.polymer.2005.06.106
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_28743108</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0032386105009420</els_id><sourcerecordid>28628288</sourcerecordid><originalsourceid>FETCH-LOGICAL-c432t-931b711a1364d34a370e9b53eff9f83e9810a89df54e1afd4e0bb3a1345d3c5b3</originalsourceid><addsrcrecordid>eNqNkU2L2zAQhkXpQtPs_oSCL-3N6UiyZPm0lLAfhcCW0j0LWR41CrbllZyF_PsqTWCPm9N88My8w7yEfKGwokDl991qCv1hwLhiAGIFMrflB7KgquYlYw39SBYAnJVcSfqJfE5pBwBMsGpBfv3eYujDX29NX5ixKwa0WzP-L6cYJoyzx1QEV-TUht7M2BX2YMacFJhmjMVoxmDDMIXkZ0zX5MqZPuHNOS7J8_3dn_VjuXl6-Ln-sSltxdlcNpy2NaWGcll1vDK8BmxawdG5ximOjaJgVNM5USE1rqsQ2pZnvBIdt6LlS_LttDdf-bLPl-jBJ4t9b0YM-6SZqitOQV0ASqaYugQUshZCZFCcQBtDShGdnqIfTDxoCvroiN7psyP66IgGmdsyz309C5iU_-uiGa1Pb8M1CNXULHO3Jw7z_1593pKsx9Fi5yPaWXfBv6P0DzpxpVM</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>28567555</pqid></control><display><type>article</type><title>Rheological and mechanical properties of percolated cyanate ester nanocomposites</title><source>ScienceDirect Freedom Collection</source><creator>Wooster, Tim J. ; Abrol, Simmi ; MacFarlane, Douglas R.</creator><creatorcontrib>Wooster, Tim J. ; Abrol, Simmi ; MacFarlane, Douglas R.</creatorcontrib><description>The rheological properties and mechanical properties of percolated cyanate ester monomer/layered silicate mixtures are reported. A number of different cation exchanged montmorillonites were examined in an effort to achieve maximal montmorillonite delamination. The dispersion throughout the cyanate ester of a montmorillonite with phenylated ammonium cations (2MBHT MMT) results in the formation of a percolated network. The rheology of this percolated network undergoes a viscous liquid to elastic solid transition at 4wt% montmorillonite. The percolation of the montmorillonite in the cyanate ester results in a significant improvement in crack resistance (80%) without a sacrifice of flexural strength.</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/j.polymer.2005.06.106</identifier><identifier>CODEN: POLMAG</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Composites ; Cyanate ester ; Exact sciences and technology ; Forms of application and semi-finished materials ; Montmorillonite ; Polymer industry, paints, wood ; Rheology ; Technology of polymers</subject><ispartof>Polymer (Guilford), 2005-09, Vol.46 (19), p.8011-8017</ispartof><rights>2005 Elsevier Ltd</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c432t-931b711a1364d34a370e9b53eff9f83e9810a89df54e1afd4e0bb3a1345d3c5b3</citedby><cites>FETCH-LOGICAL-c432t-931b711a1364d34a370e9b53eff9f83e9810a89df54e1afd4e0bb3a1345d3c5b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=17058972$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Wooster, Tim J.</creatorcontrib><creatorcontrib>Abrol, Simmi</creatorcontrib><creatorcontrib>MacFarlane, Douglas R.</creatorcontrib><title>Rheological and mechanical properties of percolated cyanate ester nanocomposites</title><title>Polymer (Guilford)</title><description>The rheological properties and mechanical properties of percolated cyanate ester monomer/layered silicate mixtures are reported. A number of different cation exchanged montmorillonites were examined in an effort to achieve maximal montmorillonite delamination. The dispersion throughout the cyanate ester of a montmorillonite with phenylated ammonium cations (2MBHT MMT) results in the formation of a percolated network. The rheology of this percolated network undergoes a viscous liquid to elastic solid transition at 4wt% montmorillonite. The percolation of the montmorillonite in the cyanate ester results in a significant improvement in crack resistance (80%) without a sacrifice of flexural strength.</description><subject>Applied sciences</subject><subject>Composites</subject><subject>Cyanate ester</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>Montmorillonite</subject><subject>Polymer industry, paints, wood</subject><subject>Rheology</subject><subject>Technology of polymers</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNqNkU2L2zAQhkXpQtPs_oSCL-3N6UiyZPm0lLAfhcCW0j0LWR41CrbllZyF_PsqTWCPm9N88My8w7yEfKGwokDl991qCv1hwLhiAGIFMrflB7KgquYlYw39SBYAnJVcSfqJfE5pBwBMsGpBfv3eYujDX29NX5ixKwa0WzP-L6cYJoyzx1QEV-TUht7M2BX2YMacFJhmjMVoxmDDMIXkZ0zX5MqZPuHNOS7J8_3dn_VjuXl6-Ln-sSltxdlcNpy2NaWGcll1vDK8BmxawdG5ximOjaJgVNM5USE1rqsQ2pZnvBIdt6LlS_LttDdf-bLPl-jBJ4t9b0YM-6SZqitOQV0ASqaYugQUshZCZFCcQBtDShGdnqIfTDxoCvroiN7psyP66IgGmdsyz309C5iU_-uiGa1Pb8M1CNXULHO3Jw7z_1593pKsx9Fi5yPaWXfBv6P0DzpxpVM</recordid><startdate>20050908</startdate><enddate>20050908</enddate><creator>Wooster, Tim J.</creator><creator>Abrol, Simmi</creator><creator>MacFarlane, Douglas R.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>F28</scope><scope>FR3</scope></search><sort><creationdate>20050908</creationdate><title>Rheological and mechanical properties of percolated cyanate ester nanocomposites</title><author>Wooster, Tim J. ; Abrol, Simmi ; MacFarlane, Douglas R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c432t-931b711a1364d34a370e9b53eff9f83e9810a89df54e1afd4e0bb3a1345d3c5b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Applied sciences</topic><topic>Composites</topic><topic>Cyanate ester</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>Montmorillonite</topic><topic>Polymer industry, paints, wood</topic><topic>Rheology</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wooster, Tim J.</creatorcontrib><creatorcontrib>Abrol, Simmi</creatorcontrib><creatorcontrib>MacFarlane, Douglas R.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ANTE: Abstracts in New Technology &amp; Engineering</collection><collection>Engineering Research Database</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wooster, Tim J.</au><au>Abrol, Simmi</au><au>MacFarlane, Douglas R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rheological and mechanical properties of percolated cyanate ester nanocomposites</atitle><jtitle>Polymer (Guilford)</jtitle><date>2005-09-08</date><risdate>2005</risdate><volume>46</volume><issue>19</issue><spage>8011</spage><epage>8017</epage><pages>8011-8017</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><coden>POLMAG</coden><abstract>The rheological properties and mechanical properties of percolated cyanate ester monomer/layered silicate mixtures are reported. A number of different cation exchanged montmorillonites were examined in an effort to achieve maximal montmorillonite delamination. The dispersion throughout the cyanate ester of a montmorillonite with phenylated ammonium cations (2MBHT MMT) results in the formation of a percolated network. The rheology of this percolated network undergoes a viscous liquid to elastic solid transition at 4wt% montmorillonite. The percolation of the montmorillonite in the cyanate ester results in a significant improvement in crack resistance (80%) without a sacrifice of flexural strength.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.polymer.2005.06.106</doi><tpages>7</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0032-3861
ispartof Polymer (Guilford), 2005-09, Vol.46 (19), p.8011-8017
issn 0032-3861
1873-2291
language eng
recordid cdi_proquest_miscellaneous_28743108
source ScienceDirect Freedom Collection
subjects Applied sciences
Composites
Cyanate ester
Exact sciences and technology
Forms of application and semi-finished materials
Montmorillonite
Polymer industry, paints, wood
Rheology
Technology of polymers
title Rheological and mechanical properties of percolated cyanate ester nanocomposites
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-27T06%3A53%3A32IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Rheological%20and%20mechanical%20properties%20of%20percolated%20cyanate%20ester%20nanocomposites&rft.jtitle=Polymer%20(Guilford)&rft.au=Wooster,%20Tim%20J.&rft.date=2005-09-08&rft.volume=46&rft.issue=19&rft.spage=8011&rft.epage=8017&rft.pages=8011-8017&rft.issn=0032-3861&rft.eissn=1873-2291&rft.coden=POLMAG&rft_id=info:doi/10.1016/j.polymer.2005.06.106&rft_dat=%3Cproquest_cross%3E28628288%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c432t-931b711a1364d34a370e9b53eff9f83e9810a89df54e1afd4e0bb3a1345d3c5b3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=28567555&rft_id=info:pmid/&rfr_iscdi=true