Modular Synthesis of Biphen[n]arenes Directed by Five-Membered Heterocycles

Modular synthesis of novel biphen­[n]­arenes (n = 2–4) with customizable heterocycle blocks, functional skeletons, binding sites, and topological structures could be facilely achieved through the rational design and replacement of reaction modules (furan and thiophene), functional modules (substitut...

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Published in:Organic letters 2023-11, Vol.25 (43), p.7836-7840
Main Authors: Li, Zhao-Xian, Du, Xu-Sheng, Wang, Jing, Wu, Zhuo-Qian, Zheng, Zhe, Yao, Shibo, Wang, Bin, Li, Chunju
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cited_by cdi_FETCH-LOGICAL-a322t-24628dfac385be84ad613e5abcc2f53dcbc1bf40085427f44a4139bcc332ba8e3
cites cdi_FETCH-LOGICAL-a322t-24628dfac385be84ad613e5abcc2f53dcbc1bf40085427f44a4139bcc332ba8e3
container_end_page 7840
container_issue 43
container_start_page 7836
container_title Organic letters
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creator Li, Zhao-Xian
Du, Xu-Sheng
Wang, Jing
Wu, Zhuo-Qian
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Yao, Shibo
Wang, Bin
Li, Chunju
description Modular synthesis of novel biphen­[n]­arenes (n = 2–4) with customizable heterocycle blocks, functional skeletons, binding sites, and topological structures could be facilely achieved through the rational design and replacement of reaction modules (furan and thiophene), functional modules (substituted benzene, biphenyl, and naphthalene), and linking modules (methylene). These biphen­[n]­arenes were characterized by NMR, HRMS, and X-ray crystalline diffraction, complemented by DFT calculations. Their photophysical properties were thoroughly studied.
doi_str_mv 10.1021/acs.orglett.3c03078
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title Modular Synthesis of Biphen[n]arenes Directed by Five-Membered Heterocycles
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