Quantifying the roles of thermal volatilization and decomposition in microwave remediation of polycyclic aromatic hydrocarbon–polluted soil and modeling remediation effectiveness

Microwave irradiation is a promising technology for the remediation of soil contaminated by organic contaminants. However, the roles of volatilization and decomposition in microwave removal of polycyclic aromatic hydrocarbons (PAHs) in soil have not yet been quantitatively determined. A model descri...

Full description

Saved in:
Bibliographic Details
Published in:Journal of hazardous materials 2024-02, Vol.463, p.132884-132884, Article 132884
Main Authors: Deng, Jibao, Wang, Hefei, Su, Yan, Shen, Ke, Chen, Xuwen, Zhou, Xian, Hu, Xiaojie, Gao, Yanzheng
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c286t-9b0fbded8f84aef170e4c574d8a9dc72f2a971ecd011741d065766a04dc334f63
cites cdi_FETCH-LOGICAL-c286t-9b0fbded8f84aef170e4c574d8a9dc72f2a971ecd011741d065766a04dc334f63
container_end_page 132884
container_issue
container_start_page 132884
container_title Journal of hazardous materials
container_volume 463
creator Deng, Jibao
Wang, Hefei
Su, Yan
Shen, Ke
Chen, Xuwen
Zhou, Xian
Hu, Xiaojie
Gao, Yanzheng
description Microwave irradiation is a promising technology for the remediation of soil contaminated by organic contaminants. However, the roles of volatilization and decomposition in microwave removal of polycyclic aromatic hydrocarbons (PAHs) in soil have not yet been quantitatively determined. A model describing the removal efficiency of benz(a)anthracene (BaA) at different treatment times and varied conditions was constructed, wherein BaA removal efficiency was positively and linearly correlated with soil temperature. BaA removal in soil was attributed to thermal volatilization (97.8%) and decomposition (2.2%). Radicals such as ∙OH and ∙O 2- were found to initiate BaA decomposition, the pathway of which was elucidated through HPLC-MS analysis, revealing benz(a)anthracene-7,12-dione as the main intermediate product. The new ideas and perspectives founded in this study offer theoretical support for microwave remediation of organic compound-contaminated sites.
doi_str_mv 10.1016/j.jhazmat.2023.132884
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2885537628</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2885537628</sourcerecordid><originalsourceid>FETCH-LOGICAL-c286t-9b0fbded8f84aef170e4c574d8a9dc72f2a971ecd011741d065766a04dc334f63</originalsourceid><addsrcrecordid>eNpNUctqGzEUFaWBuk4-oaBlNzORRpqRvCyheYAhBNK1kKWrWEYzcqWxy2SVf-iv5IvyJZHtLLK5L849HM5B6AclNSW0u9zUm7V-7vVYN6RhNWWNlPwLmlEpWMUY676iGWGEV0wu-Df0PecNIYSKls_Q68NOD6N3kx-e8LgGnGKAjKM7LKnXAe9j0KMP_rnUOGA9WGzBxH4bsz9e_IB7b1L8p_flHXqw_gQtJNsYJjOZ4A3WKRaJZVhPNkWj0yoOby__CyLsRrA4Rx-O7H20EA5yPnOBc2BGv4cBcj5HZ06HDBcffY7-XP9-vLqtlvc3d1e_lpVpZDdWixVxKwtWOsk1OCoIcNMKbqVeWCMa1-iFoGAsoVRwaknXiq7ThFvDGHcdm6OfJ95tin93kEfV-2wgBD1A3GVVfG5bJrpGFmh7ghYjck7g1Db5XqdJUaIOKamN-khJHVJSp5TYO50ekK0</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2885537628</pqid></control><display><type>article</type><title>Quantifying the roles of thermal volatilization and decomposition in microwave remediation of polycyclic aromatic hydrocarbon–polluted soil and modeling remediation effectiveness</title><source>Elsevier</source><creator>Deng, Jibao ; Wang, Hefei ; Su, Yan ; Shen, Ke ; Chen, Xuwen ; Zhou, Xian ; Hu, Xiaojie ; Gao, Yanzheng</creator><creatorcontrib>Deng, Jibao ; Wang, Hefei ; Su, Yan ; Shen, Ke ; Chen, Xuwen ; Zhou, Xian ; Hu, Xiaojie ; Gao, Yanzheng</creatorcontrib><description>Microwave irradiation is a promising technology for the remediation of soil contaminated by organic contaminants. However, the roles of volatilization and decomposition in microwave removal of polycyclic aromatic hydrocarbons (PAHs) in soil have not yet been quantitatively determined. A model describing the removal efficiency of benz(a)anthracene (BaA) at different treatment times and varied conditions was constructed, wherein BaA removal efficiency was positively and linearly correlated with soil temperature. BaA removal in soil was attributed to thermal volatilization (97.8%) and decomposition (2.2%). Radicals such as ∙OH and ∙O 2- were found to initiate BaA decomposition, the pathway of which was elucidated through HPLC-MS analysis, revealing benz(a)anthracene-7,12-dione as the main intermediate product. The new ideas and perspectives founded in this study offer theoretical support for microwave remediation of organic compound-contaminated sites.</description><identifier>ISSN: 0304-3894</identifier><identifier>EISSN: 1873-3336</identifier><identifier>DOI: 10.1016/j.jhazmat.2023.132884</identifier><language>eng</language><ispartof>Journal of hazardous materials, 2024-02, Vol.463, p.132884-132884, Article 132884</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c286t-9b0fbded8f84aef170e4c574d8a9dc72f2a971ecd011741d065766a04dc334f63</citedby><cites>FETCH-LOGICAL-c286t-9b0fbded8f84aef170e4c574d8a9dc72f2a971ecd011741d065766a04dc334f63</cites><orcidid>0000-0002-3814-3555</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Deng, Jibao</creatorcontrib><creatorcontrib>Wang, Hefei</creatorcontrib><creatorcontrib>Su, Yan</creatorcontrib><creatorcontrib>Shen, Ke</creatorcontrib><creatorcontrib>Chen, Xuwen</creatorcontrib><creatorcontrib>Zhou, Xian</creatorcontrib><creatorcontrib>Hu, Xiaojie</creatorcontrib><creatorcontrib>Gao, Yanzheng</creatorcontrib><title>Quantifying the roles of thermal volatilization and decomposition in microwave remediation of polycyclic aromatic hydrocarbon–polluted soil and modeling remediation effectiveness</title><title>Journal of hazardous materials</title><description>Microwave irradiation is a promising technology for the remediation of soil contaminated by organic contaminants. However, the roles of volatilization and decomposition in microwave removal of polycyclic aromatic hydrocarbons (PAHs) in soil have not yet been quantitatively determined. A model describing the removal efficiency of benz(a)anthracene (BaA) at different treatment times and varied conditions was constructed, wherein BaA removal efficiency was positively and linearly correlated with soil temperature. BaA removal in soil was attributed to thermal volatilization (97.8%) and decomposition (2.2%). Radicals such as ∙OH and ∙O 2- were found to initiate BaA decomposition, the pathway of which was elucidated through HPLC-MS analysis, revealing benz(a)anthracene-7,12-dione as the main intermediate product. The new ideas and perspectives founded in this study offer theoretical support for microwave remediation of organic compound-contaminated sites.</description><issn>0304-3894</issn><issn>1873-3336</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpNUctqGzEUFaWBuk4-oaBlNzORRpqRvCyheYAhBNK1kKWrWEYzcqWxy2SVf-iv5IvyJZHtLLK5L849HM5B6AclNSW0u9zUm7V-7vVYN6RhNWWNlPwLmlEpWMUY676iGWGEV0wu-Df0PecNIYSKls_Q68NOD6N3kx-e8LgGnGKAjKM7LKnXAe9j0KMP_rnUOGA9WGzBxH4bsz9e_IB7b1L8p_flHXqw_gQtJNsYJjOZ4A3WKRaJZVhPNkWj0yoOby__CyLsRrA4Rx-O7H20EA5yPnOBc2BGv4cBcj5HZ06HDBcffY7-XP9-vLqtlvc3d1e_lpVpZDdWixVxKwtWOsk1OCoIcNMKbqVeWCMa1-iFoGAsoVRwaknXiq7ThFvDGHcdm6OfJ95tin93kEfV-2wgBD1A3GVVfG5bJrpGFmh7ghYjck7g1Db5XqdJUaIOKamN-khJHVJSp5TYO50ekK0</recordid><startdate>20240205</startdate><enddate>20240205</enddate><creator>Deng, Jibao</creator><creator>Wang, Hefei</creator><creator>Su, Yan</creator><creator>Shen, Ke</creator><creator>Chen, Xuwen</creator><creator>Zhou, Xian</creator><creator>Hu, Xiaojie</creator><creator>Gao, Yanzheng</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-3814-3555</orcidid></search><sort><creationdate>20240205</creationdate><title>Quantifying the roles of thermal volatilization and decomposition in microwave remediation of polycyclic aromatic hydrocarbon–polluted soil and modeling remediation effectiveness</title><author>Deng, Jibao ; Wang, Hefei ; Su, Yan ; Shen, Ke ; Chen, Xuwen ; Zhou, Xian ; Hu, Xiaojie ; Gao, Yanzheng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c286t-9b0fbded8f84aef170e4c574d8a9dc72f2a971ecd011741d065766a04dc334f63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Deng, Jibao</creatorcontrib><creatorcontrib>Wang, Hefei</creatorcontrib><creatorcontrib>Su, Yan</creatorcontrib><creatorcontrib>Shen, Ke</creatorcontrib><creatorcontrib>Chen, Xuwen</creatorcontrib><creatorcontrib>Zhou, Xian</creatorcontrib><creatorcontrib>Hu, Xiaojie</creatorcontrib><creatorcontrib>Gao, Yanzheng</creatorcontrib><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of hazardous materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Deng, Jibao</au><au>Wang, Hefei</au><au>Su, Yan</au><au>Shen, Ke</au><au>Chen, Xuwen</au><au>Zhou, Xian</au><au>Hu, Xiaojie</au><au>Gao, Yanzheng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Quantifying the roles of thermal volatilization and decomposition in microwave remediation of polycyclic aromatic hydrocarbon–polluted soil and modeling remediation effectiveness</atitle><jtitle>Journal of hazardous materials</jtitle><date>2024-02-05</date><risdate>2024</risdate><volume>463</volume><spage>132884</spage><epage>132884</epage><pages>132884-132884</pages><artnum>132884</artnum><issn>0304-3894</issn><eissn>1873-3336</eissn><abstract>Microwave irradiation is a promising technology for the remediation of soil contaminated by organic contaminants. However, the roles of volatilization and decomposition in microwave removal of polycyclic aromatic hydrocarbons (PAHs) in soil have not yet been quantitatively determined. A model describing the removal efficiency of benz(a)anthracene (BaA) at different treatment times and varied conditions was constructed, wherein BaA removal efficiency was positively and linearly correlated with soil temperature. BaA removal in soil was attributed to thermal volatilization (97.8%) and decomposition (2.2%). Radicals such as ∙OH and ∙O 2- were found to initiate BaA decomposition, the pathway of which was elucidated through HPLC-MS analysis, revealing benz(a)anthracene-7,12-dione as the main intermediate product. The new ideas and perspectives founded in this study offer theoretical support for microwave remediation of organic compound-contaminated sites.</abstract><doi>10.1016/j.jhazmat.2023.132884</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0002-3814-3555</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0304-3894
ispartof Journal of hazardous materials, 2024-02, Vol.463, p.132884-132884, Article 132884
issn 0304-3894
1873-3336
language eng
recordid cdi_proquest_miscellaneous_2885537628
source Elsevier
title Quantifying the roles of thermal volatilization and decomposition in microwave remediation of polycyclic aromatic hydrocarbon–polluted soil and modeling remediation effectiveness
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-01T06%3A55%3A14IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Quantifying%20the%20roles%20of%20thermal%20volatilization%20and%20decomposition%20in%20microwave%20remediation%20of%20polycyclic%20aromatic%20hydrocarbon%E2%80%93polluted%20soil%20and%20modeling%20remediation%20effectiveness&rft.jtitle=Journal%20of%20hazardous%20materials&rft.au=Deng,%20Jibao&rft.date=2024-02-05&rft.volume=463&rft.spage=132884&rft.epage=132884&rft.pages=132884-132884&rft.artnum=132884&rft.issn=0304-3894&rft.eissn=1873-3336&rft_id=info:doi/10.1016/j.jhazmat.2023.132884&rft_dat=%3Cproquest_cross%3E2885537628%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c286t-9b0fbded8f84aef170e4c574d8a9dc72f2a971ecd011741d065766a04dc334f63%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2885537628&rft_id=info:pmid/&rfr_iscdi=true