Studies on thermal, thermal ageing and morphological characteristics of EPDM-g-VTES/LLDPE

• Published in: European polymer journal 2006-02, Vol.42 (2), p.336-347
• Main Authors: Alagar, M., Majeed, S.M. Abdul, Selvaganapathi, A., Gnanasundaram, P.
• Format: Article
• Language: English
• Subjects: Applied sciences; Chemical modifications; Chemical reactions and properties; EPDM-g-VTES/LLDPE blends; Exact sciences and technology; Morphology; Organic polymers; Physicochemistry of polymers; Thermal properties
• ISSN: 0014-3057; 1873-1945
• DOI: 10.1016/j.eurpolymj.2005.07.013

A novel graft copolymer of vinyltriethoxysilane onto ethylene propylene diene terpolymer has been developed by grafting varying contents of VTES using dicumyl peroxide as an initiator in a twin-screw extruder. Grafting of VTES and EPDM has been ascertained using FTIR. The EPDM-g-VTES developed has been blended with different weight percentage of linear low density polyethylene [LLDPE] by melt mixing. Thermal, thermal ageing and morphological behaviour of the blends are studied with respect to the effect of blend composition, static vulcanization and dynamic vulcanization with varying quantities of VTES and LLDPE. The incorporation of silane moiety onto EPDM raises the inception and final decomposition temperature. The stability EPDM-g-VTES/LLDPE blend increases with increase in concentration of EPDM-g-VTES due to thermally stable Si–O–Si linkage. It was ascertain from SEM micrograph that EPDM-g-VTES/LLDPE blends lead to formation of interpenetrating crosslinked network during hot water treatment and by treatment with DCP, respectively. The linear, statically vulcanized, dynamically vulcanized and filled blends of EPDM-g-VTES/LLDPE have been characterized to assess the suitability of the blends for high performance applications. In addition, it is also observed that the incorporation of fillers improves thermal stability of the blends.