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Formation of 2D supramolecular architectures at electrochemical solid/liquid interfaces
The controlled formation of supramolecular architectures on chloride pre-covered Cu(1 0 0) has been studied by means of in situ scanning tunneling microscopy (STM) in an electrochemical environment. On top of the c(2 × 2)-Cl layer, ordered arrays of supramolecular cavitand structures could be obtain...
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| Published in: | Electrochimica acta 2005-08, Vol.50 (21), p.4257-4268 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c442t-70b94960cf177ebe7ec95b60fdc37cfd61a5ca863f1e0c54cd4aa2a8cee2a2103 |
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| cites | cdi_FETCH-LOGICAL-c442t-70b94960cf177ebe7ec95b60fdc37cfd61a5ca863f1e0c54cd4aa2a8cee2a2103 |
| container_end_page | 4268 |
| container_issue | 21 |
| container_start_page | 4257 |
| container_title | Electrochimica acta |
| container_volume | 50 |
| creator | Safarowsky, C. Rang, A. Schalley, C.A. Wandelt, K. Broekmann, P. |
| description | The controlled formation of supramolecular architectures on chloride pre-covered Cu(1
0
0) has been studied by means of in situ scanning tunneling microscopy (STM) in an electrochemical environment. On top of the
c(2
×
2)-Cl layer, ordered arrays of supramolecular cavitand structures could be obtained either by a
surface assisted assembly of monomer building-blocks (1,1′-dibenzyl-4,4′-bipyridinium molecules) or by a
direct adsorption of supramolecular assemblies (metallo-supramolecular squares) from the solution phase. Besides the omnipresent van-der-Waals-like interactions additional electrostatic interactions between the anionic chloride layer and the positively charged (metallo)-organic molecules are supposed to have strong impact on the 2D phase behavior in both cases.
The obtained supramolecular entities with their cavities oriented towards the solution phase can be regarded as potential host assemblies for the specific inclusion of guest molecules. |
| doi_str_mv | 10.1016/j.electacta.2005.03.068 |
| format | article |
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0
0) has been studied by means of in situ scanning tunneling microscopy (STM) in an electrochemical environment. On top of the
c(2
×
2)-Cl layer, ordered arrays of supramolecular cavitand structures could be obtained either by a
surface assisted assembly of monomer building-blocks (1,1′-dibenzyl-4,4′-bipyridinium molecules) or by a
direct adsorption of supramolecular assemblies (metallo-supramolecular squares) from the solution phase. Besides the omnipresent van-der-Waals-like interactions additional electrostatic interactions between the anionic chloride layer and the positively charged (metallo)-organic molecules are supposed to have strong impact on the 2D phase behavior in both cases.
The obtained supramolecular entities with their cavities oriented towards the solution phase can be regarded as potential host assemblies for the specific inclusion of guest molecules.</description><identifier>ISSN: 0013-4686</identifier><identifier>EISSN: 1873-3859</identifier><identifier>DOI: 10.1016/j.electacta.2005.03.068</identifier><identifier>CODEN: ELCAAV</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Adsorption ; Cavitand structures ; Chemistry ; Copper electrochemistry ; Electrochemistry ; Exact sciences and technology ; General and physical chemistry ; Scanning tunneling microscopy ; Self-assembly ; Specific anion adsorption ; Study of interfaces ; Supramolecular chemistry ; Surface science ; Template effects</subject><ispartof>Electrochimica acta, 2005-08, Vol.50 (21), p.4257-4268</ispartof><rights>2005 Elsevier Ltd</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c442t-70b94960cf177ebe7ec95b60fdc37cfd61a5ca863f1e0c54cd4aa2a8cee2a2103</citedby><cites>FETCH-LOGICAL-c442t-70b94960cf177ebe7ec95b60fdc37cfd61a5ca863f1e0c54cd4aa2a8cee2a2103</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>309,310,314,780,784,789,790,23921,23922,25131,27915,27916</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17007583$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Safarowsky, C.</creatorcontrib><creatorcontrib>Rang, A.</creatorcontrib><creatorcontrib>Schalley, C.A.</creatorcontrib><creatorcontrib>Wandelt, K.</creatorcontrib><creatorcontrib>Broekmann, P.</creatorcontrib><title>Formation of 2D supramolecular architectures at electrochemical solid/liquid interfaces</title><title>Electrochimica acta</title><description>The controlled formation of supramolecular architectures on chloride pre-covered Cu(1
0
0) has been studied by means of in situ scanning tunneling microscopy (STM) in an electrochemical environment. On top of the
c(2
×
2)-Cl layer, ordered arrays of supramolecular cavitand structures could be obtained either by a
surface assisted assembly of monomer building-blocks (1,1′-dibenzyl-4,4′-bipyridinium molecules) or by a
direct adsorption of supramolecular assemblies (metallo-supramolecular squares) from the solution phase. Besides the omnipresent van-der-Waals-like interactions additional electrostatic interactions between the anionic chloride layer and the positively charged (metallo)-organic molecules are supposed to have strong impact on the 2D phase behavior in both cases.
The obtained supramolecular entities with their cavities oriented towards the solution phase can be regarded as potential host assemblies for the specific inclusion of guest molecules.</description><subject>Adsorption</subject><subject>Cavitand structures</subject><subject>Chemistry</subject><subject>Copper electrochemistry</subject><subject>Electrochemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Scanning tunneling microscopy</subject><subject>Self-assembly</subject><subject>Specific anion adsorption</subject><subject>Study of interfaces</subject><subject>Supramolecular chemistry</subject><subject>Surface science</subject><subject>Template effects</subject><issn>0013-4686</issn><issn>1873-3859</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNqFkE1r3DAQhkVJoZukv6G-tDc7I8uWtMeQJm0g0EtDj2J2PCJabGsj2YX--2i7oT0GBubyfvA-QnyS0EiQ-mrf8Mi0YLmmBegbUA1o-05spDWqVrbfnokNgFR1p63-IM5z3gOA0QY24tddTBMuIc5V9FX7tcrrIeEUS-Q6Yqow0VNYSv6aOFe4VH_LUqQnngLhWOU4huFqDM9rGKowL5w8EudL8d7jmPnj678Qj3e3P2--1w8_vt3fXD_U1HXtUhvYbbutBvLSGN6xYdr2Ow1-IGXID1piT2i18pKB-o6GDrFFS8wtthLUhfhyyj2k-LxyXtwUMvE44sxxza611uheqiI0JyGlmHNi7w4pTJj-OAnuCNLt3T-Q7gjSgXIFZHF-fq3AXBb7hDOF_N9uCsveHhuuTzoue38HTi5T4Jl4CKnkuiGGN7teAPuqj_8</recordid><startdate>20050801</startdate><enddate>20050801</enddate><creator>Safarowsky, C.</creator><creator>Rang, A.</creator><creator>Schalley, C.A.</creator><creator>Wandelt, K.</creator><creator>Broekmann, P.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20050801</creationdate><title>Formation of 2D supramolecular architectures at electrochemical solid/liquid interfaces</title><author>Safarowsky, C. ; Rang, A. ; Schalley, C.A. ; Wandelt, K. ; Broekmann, P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c442t-70b94960cf177ebe7ec95b60fdc37cfd61a5ca863f1e0c54cd4aa2a8cee2a2103</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Adsorption</topic><topic>Cavitand structures</topic><topic>Chemistry</topic><topic>Copper electrochemistry</topic><topic>Electrochemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Scanning tunneling microscopy</topic><topic>Self-assembly</topic><topic>Specific anion adsorption</topic><topic>Study of interfaces</topic><topic>Supramolecular chemistry</topic><topic>Surface science</topic><topic>Template effects</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Safarowsky, C.</creatorcontrib><creatorcontrib>Rang, A.</creatorcontrib><creatorcontrib>Schalley, C.A.</creatorcontrib><creatorcontrib>Wandelt, K.</creatorcontrib><creatorcontrib>Broekmann, P.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Electrochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Safarowsky, C.</au><au>Rang, A.</au><au>Schalley, C.A.</au><au>Wandelt, K.</au><au>Broekmann, P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Formation of 2D supramolecular architectures at electrochemical solid/liquid interfaces</atitle><jtitle>Electrochimica acta</jtitle><date>2005-08-01</date><risdate>2005</risdate><volume>50</volume><issue>21</issue><spage>4257</spage><epage>4268</epage><pages>4257-4268</pages><issn>0013-4686</issn><eissn>1873-3859</eissn><coden>ELCAAV</coden><abstract>The controlled formation of supramolecular architectures on chloride pre-covered Cu(1
0
0) has been studied by means of in situ scanning tunneling microscopy (STM) in an electrochemical environment. On top of the
c(2
×
2)-Cl layer, ordered arrays of supramolecular cavitand structures could be obtained either by a
surface assisted assembly of monomer building-blocks (1,1′-dibenzyl-4,4′-bipyridinium molecules) or by a
direct adsorption of supramolecular assemblies (metallo-supramolecular squares) from the solution phase. Besides the omnipresent van-der-Waals-like interactions additional electrostatic interactions between the anionic chloride layer and the positively charged (metallo)-organic molecules are supposed to have strong impact on the 2D phase behavior in both cases.
The obtained supramolecular entities with their cavities oriented towards the solution phase can be regarded as potential host assemblies for the specific inclusion of guest molecules.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.electacta.2005.03.068</doi><tpages>12</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0013-4686 |
| ispartof | Electrochimica acta, 2005-08, Vol.50 (21), p.4257-4268 |
| issn | 0013-4686 1873-3859 |
| language | eng |
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| source | ScienceDirect Freedom Collection |
| subjects | Adsorption Cavitand structures Chemistry Copper electrochemistry Electrochemistry Exact sciences and technology General and physical chemistry Scanning tunneling microscopy Self-assembly Specific anion adsorption Study of interfaces Supramolecular chemistry Surface science Template effects |
| title | Formation of 2D supramolecular architectures at electrochemical solid/liquid interfaces |
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