Agricultural abandoned lands as emission sources of dust containing metals and pesticides in the Sonora-Arizona Desert

• Published in: Environmental monitoring and assessment 2023-12, Vol.195 (12), p.1496-1496, Article 1496
• Main Authors: Bracamonte-Terán, Jesús Arturo, Meza-Figueroa, Diana, García-Rico, Leticia, Schiavo, Benedetto, Meza-Montenegro, María Mercedes, Valenzuela-Quintanar, Ana Isabel
• Format: Article
• Language: English
• Subjects: Abandoned land; Agricultural land; Agriculture; Air masses; Aquifers; Arizona; Arsenic; Atmospheric particulates; Atmospheric Protection/Air Quality Control/Air Pollution; Atmospheric transport; Bans; Chemical analysis; Chromatography; Cities; Coastal aquifers; Contamination; Copper; Dust; Earth and Environmental Science; Ecology; Ecotoxicology; Emissions; Emitters; Environment; Environmental Management; Environmental Monitoring; Fluorescence; Gas chromatography; Heavy metals; Humans; Iron; Lead; Manganese; Metals; Monitoring/Environmental Analysis; Particle trajectories; Pesticides; Pollution dispersion; Principal components analysis; Saline water intrusion; Salt water intrusion; Seawater; Seawater intrusion; Soil contamination; Titanium; Tracers; Vanadium; Water analysis; Wind; X-ray fluorescence; Zinc; Zirconium
• ISSN: 0167-6369; 1573-2959
• DOI: 10.1007/s10661-023-12086-9

This investigation examines the transport of metal- and pesticide-polluted dust emitted by one of the most relevant agricultural areas of Northwestern Mexico. In the contaminated area, an excessive water extraction of the aquifer and seawater intrusion caused the abandonment of fields, which are pollutant-loaded dust emitters. We used air mass forward trajectories (HYSPLIT) model to obtain particle trajectories in the wind and the use of banned pesticides as geochemical tracers for dust transported by wind. Fifty dust samples from 10 agriculture fields and 26 roof dust of a city close to the agricultural area were analyzed for their contents of zirconium, lead, arsenic, zinc, copper, iron, manganese, vanadium, and titanium, by portable X-ray fluorescence. Nine pesticides were analyzed in the roof dust and agricultural soil samples by gas chromatography. Results show that the distribution of metals was significantly different between active and abandoned fields. Arsenic-lead-copper was mainly concentrated in abandoned fields, while zinc-iron-manganese-titanium was dominant in active fields. Two potential sources of metal contamination were found by principal component analysis (PCA): (I) a mixture of traffic and agricultural sources and (II) a group related to agricultural activities. The occurrence of banned pesticides in dust deposited on roofs collected at nearby cities confirms the atmospheric transport from the agricultural area. The HYSPLIT results indicated that the dust emitted from agricultural fields can reach up to the neighboring states of Sonora, Mexico, and the USA. The impacts that these emissions can have on human health should be studied in future research.