Synthesis of unsymmetrical ketones via dual catalysed cross-coupling of α,β-unsaturated carboxylic acids with aryldiazonium salts

A visible light-enabled synthesis of unsymmetrical ketones has been accomplished by the cross-coupling of α,β-unsaturated carboxylic acids and aryldiazonium salts embracing a synergistic eosin Y and Co(OAc) ·4H O catalysis. The reaction involves decarboxylative aerobic CC bond cleavage, and is endo...

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Published in:Chemical communications (Cambridge, England) England), 2023-12, Vol.59 (100), p.14827-14830
Main Authors: Chand, Shiv, Sharma, Anup Kumar, Pandey, Anand Kumar, Singh, Krishna Nand
Format: Article
Language:English
Subjects:
Carboxylic acids
Chemical synthesis
Cross coupling
Ketones
Substrates
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description A visible light-enabled synthesis of unsymmetrical ketones has been accomplished by the cross-coupling of α,β-unsaturated carboxylic acids and aryldiazonium salts embracing a synergistic eosin Y and Co(OAc) ·4H O catalysis. The reaction involves decarboxylative aerobic CC bond cleavage, and is endowed with the creation of new C-C and C-O bonds with good substrate scope.
doi_str_mv 10.1039/d3cc04898e
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source Royal Society of Chemistry
subjects Carboxylic acids
Chemical synthesis
Cross coupling
Ketones
Substrates
title Synthesis of unsymmetrical ketones via dual catalysed cross-coupling of α,β-unsaturated carboxylic acids with aryldiazonium salts
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