9,9'-Bis- o -carboranes: synthesis and exploration of properties

A highly efficient Pd-catalyzed B(9)-H/B(9)-H oxidative dehydrogenation coupling of carboranes to synthesize 9,9'-bis- -carboranes has been developed. The properties and derivatization of 9,9'-bis- -carborane were also examined, which provided diverse bis- -carborane derivatives and bis- -...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2024-01, Vol.60 (5), p.614-617
Main Authors: Chen, Feijing, Guo, Wenjing, Ma, Yan-Na, Chen, Xuenian
Format: Article
Language:English
Subjects:
Carborane
Dehydrogenation
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Summary:A highly efficient Pd-catalyzed B(9)-H/B(9)-H oxidative dehydrogenation coupling of carboranes to synthesize 9,9'-bis- -carboranes has been developed. The properties and derivatization of 9,9'-bis- -carborane were also examined, which provided diverse bis- -carborane derivatives and bis- -carborane.
ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc05041f