Dopant effect on the optical and thermal properties of the 2D organic–inorganic hybrid perovskite (HDA)2PbBr4

• Published in: Dalton transactions : an international journal of inorganic chemistry 2024-01, Vol.53 (4), p.1691-1697
• Main Authors: Lin, Zhi, Wu, Ya-Nan, Si-Yu, Xu, Bi-Cui, Chen, Pei-Wen, Huang, Xing-Hui, Qi, Yang-Peng, Lin, Ke-Zhao, Du
• Format: Article
• Language: English
• Subjects: Bismuth; Crystallization; Dopamine; Dopants; Energy transfer; Optical properties; Perovskites; Phase transitions; Temperature dependence; Thermodynamic properties
• ISSN: 1477-9226; 1477-9234
• DOI: 10.1039/d3dt03841f

Lead-based two-dimensional organic–inorganic hybrid perovskites (2D HOIPs) are popular materials with various optical properties, which can be tuned through metal ion doping. Due to the size and valence misfit, metal ion dopants in 2D lead-based HOIPs are still limited. In this work, Mn2+, Sb3+ and Bi3+ are doped into 2D (HDA)2PbBr4 (HDA = protonated dopamine) successfully. As a result, the dopants in 2D (HDA)2PbBr4 can induce their characteristic optical spectra, which is studied at different temperatures and excitation powers. The temperature-dependent energy transfer in the Mn-doped sample has been clarified, in which abnormal phenomena including negative thermal quenching have been observed. In addition, the dopant ions can impact the phase transition temperatures of the samples, especially lowering their crystallization temperatures greatly. The mussel-inspired organic cation, feasible metal ion regulation, and superior stability provide (HDA)2PbBr4 potential for further applications.