Cellulose nanocrystal/graphene oxide one-dimensional photonic crystal film with excellent UV-blocking and transparency

• Published in: Carbohydrate polymers 2024-03, Vol.327, p.121646-121646, Article 121646
• Main Authors: Xia, Bingyu, Zeng, Xu, Lan, Wu, Zhang, Mingxin, Huang, Wei, Wang, Huihui, Liu, Chuanfu
• Format: Article
• Language: English
• Subjects: Cellulose nanocrystal; Chiral nematic structure; Graphene oxide; One-dimensional photonic crystal; UV-blocking
• ISSN: 0144-8617; 1879-1344
• DOI: 10.1016/j.carbpol.2023.121646

Achieving excellent ultraviolet (UV) blocking properties and maintaining high light transmittance are highly challenging. In this study, a facile and green polymer-assisted vacuum filtration strategy was used to prepare cellulose nanocrystal (CNC) one-dimensional photonic crystal (1DPhC) films with excellent UV-blocking performance and good transparency. The polymer-assisted self-assembly behaviors of CNC and the hydrogen bonding interaction between CNC, polyethylene glycol (PEG), and graphene oxide (GO) drive the homogeneous distribution and parallel alignment of GO. The UV absorption of GO and high reflection of UV resulting from the chiral nematic structure of CNCs result in excellent UV-blocking and high visible light transmission. Besides, the strong hydrogen bonding interaction among CNC, PEG, and GO endows the films with obviously increased mechanical properties. The UV-blocking and the transparency of the CNC composite films could reach 98.3 % and 60.5 %, respectively. Besides, the strain at break of the composite film reached 1.72 ± 0.11 %, which was 535.94 % of neat CNC films. The CNC composite films present great potential in the field of UV-blocking glass, sensors, anti-counterfeiting measures, radiation protection, and so on. [Display omitted]