Treatment of pulp and paper mill wastewater by polyacrylamide (PAM) in polymer induced flocculation

• Published in: Journal of hazardous materials 2006-07, Vol.135 (1), p.378-388
• Main Authors: Wong, S.S., Teng, T.T., Ahmad, A.L., Zuhairi, A., Najafpour, G.
• Format: Article
• Language: English
• Subjects: Acrylic Resins - chemistry; Anionic polyacrylamide; Applied sciences; Cationic polyacrylamide; Chemical engineering; Coagulation; Exact sciences and technology; Flocculation; General purification processes; Industrial Waste - economics; Liquid-liquid and fluid-solid mechanical separations; Nephelometry and Turbidimetry; Oxygen - chemistry; Pollution; Polyelectrolyte; Settling; Waste Disposal, Fluid - economics; Wastewaters; Water treatment and pollution
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2005.11.076

The flocculation performances of nine cationic and anionic polyacrylamides with different molecular weights and different charge densities in the treatment of pulp and paper mill wastewater have been studied. The experiments were carried out in jar tests with the polyacrylamide dosages range of 0.5–15 mg l −1, rapid mixing at 200 rpm for 2 min, followed by slow mixing at 40 rpm for 15 min and settling time of 30 min. The effectiveness of the polyacrylamides was measured based on the reduction of turbidity, the removal of total suspended solids (TSS) and the reduction of chemical oxygen demand (COD). Cationic polyacrlyamide Organopol 5415 with very high molecular weight and low charge density is found to give the highest flocculation efficiency in the treatment of the paper mill wastewater. It can achieve 95% of turbidity reduction, 98% of TSS removal, 93% of COD reduction and sludge volume index (SVI) of 14 ml g −1 at the optimum dosage of 5 mg l −1. SVI values of less than 70 ml g −1 are found for all polyacrylamide at their respective optimum dosage. Based on the cost evaluation, the use of the polyacrylamides is economically feasible to treat the pulp and paper mill wastewaters. This result suggests that single-polymer system can be used alone in the coagulation–flocculation process due to the efficiency of the polyacrylamide. Sedimentation of the sludge by gravity thickening with settling time of 30 min is possible based on the settling characteristics of the sludge produced by Organopol 5415 that can achieve 91% water recovery and 99% TSS removal after 30 min settling.