Phase change surfaces with porous metallic structures for long-term anti/de-icing application

• Published in: Journal of colloid and interface science 2024-04, Vol.660, p.136-146
• Main Authors: Yang, Deyu, Bao, Rui, Clare, Adam T., Choi, Kwing-So, Hou, Xianghui
• Format: Article
• Language: English
• Subjects: Icephobic; Interfacial interactions; Phase changeable surfaces; Quasi-liquid layer; Solid lubricant
• ISSN: 0021-9797; 1095-7103
• DOI: 10.1016/j.jcis.2024.01.091

[Display omitted] Ice mitigation has received increasing attention due to the severe safety and economic threats of icing hazards to modern industries. Slippery icephobic surface is a potential ice mitigation approach due to its ultra-low ice adhesion strength, great humidity resistance, and effective delay of ice nucleation. However, this approach currently has limited practical applications because of serious liquid depletion in the icing/de-icing process. A new strategy of phase change materials (PCM)-impregnation porous metallic structures (PIPMSs) was proposed to develop phase changeable icephobic surfaces in this study, and aimed to solve the rapid depletion via the phase changeable interfacial interactions. Evaluation of surface icephobicity and interfacial analysis proved that the phase changeable surfaces (PIPMSs) worked as an effective and durable icephobic platform by significantly delaying ice nucleation, providing long-term humid tolerance, low ice adhesion strength of as-prepared samples (less than 5 kPa), and signally improved maintaining capacity of impregnated PCMs (less than 10 % depletion) after 50 icing/de-icing cycles. To explore the interfacial responses, phase change models consisting of the unfrozen quasi-liquid layer and solid lubricant layer at the ice/PIPMSs interfaces were established, and the involved icephobic mechanisms of PIPMSs were studied based on the analysis of interfacial interactions.