Preparation and applications of novel amphiphilic fluoroalkyl end-capped oligomers-clay nanocomposites

Nonionic‐type amphiphilic fluoroalkyl end‐capped acryloylmorpholine and N,N‐dimethylacrylamide homooligomers were found to be new convenient intercalating agents for the achievement of an enlarged basal spacing of the clay layers to afford fluorinated oligomers‐clay nanocomposites. These novel fluor...

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Bibliographic Details
Published in:Polymers for advanced technologies 2006-06, Vol.17 (6), p.479-483
Main Authors: Sawada, Hideo, Takebayashi, Airi, Uejima, Mitsugu, Murakami, Toshihide
Format: Article
Language:English
Subjects:
clay
dispersibility
fluorinated polysurfactant
nanocomposites
surfactants
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Summary:Nonionic‐type amphiphilic fluoroalkyl end‐capped acryloylmorpholine and N,N‐dimethylacrylamide homooligomers were found to be new convenient intercalating agents for the achievement of an enlarged basal spacing of the clay layers to afford fluorinated oligomers‐clay nanocomposites. These novel fluoroalkyl end‐capped oligomers‐clay nanocomposites were found to exhibit good dispersibility and stability in aqueous and organic media, and were applied to the surface modification of traditional organic polymeric materials such as poly(methyl methacrylate). Copyright © 2006 John Wiley & Sons, Ltd.
ISSN:1042-7147
1099-1581
DOI:10.1002/pat.730