Electrostatically fabricated heterostructure of interfacial-polarization-enhanced Fe3O4/C/MXene for ultra-wideband electromagnetic wave absorption

• Published in: Journal of colloid and interface science 2024-05, Vol.662, p.796-806
• Main Authors: Li, Qingwei, Nan, Kai, Wang, Wei, Zheng, Hao, He, Kaikai, Wang, Yan
• Format: Article
• Language: English
• Subjects: Interfacial polarization; MOF derivative; MXene; Radar cross section; Ultra-wideband absorber
• ISSN: 0021-9797; 1095-7103
• DOI: 10.1016/j.jcis.2024.02.125

[Display omitted] Electromagnetic (EM) pollution can disrupt the functioning of advanced electronic devices, hence it’s necessary to design EM wave absorbers with high-level absorption capabilities. The Ti3C2Tx (MXene) is classified as a potential EM absorbing material; nevertheless, the lack of magnetic loss mechanism leads to its inadequate EM absorbing performance. On this basis, a novel composite design with promising EM absorption properties is hypothesized to be the integration of few-layer MXene and heterogeneous magnetic MOF derivatives (Fe3O4/C) with complementary advantages. Herein, we synthesized two-dimensional (2D) interfacial-polarization-enhanced MXene hybrid (Fe3O4/C/MXene) by electrostatic assembly. It is notable that the interfacial polarization is realized by adding a small amount of magnetic Fe3O4/C. Furthermore, the Fe3O4/C/ MXene demonstrates an astonishing effective absorption bandwidth (EAB) of 10.7 GHz and an excellent EM wave absorption performance (RLmin) of −66.9 dB. Moreover, the radar cross section (RCS) of Fe3O4/C/MXene is lower than −15.1 dB m2 from −90° to 90° with a minimum RCS value of −52.6 dB m2 at 32°. In addition, the significant attenuation of the EM wave is due to the synergistic effect of improved impedance matching, dielectric loss, and magnetic loss. Thus, the magnetized Fe3O4/C/MXene hybrid is expected to emerge as a strong contender for high-performance EM wave absorbers.