Magnus' Green Salt Revisited: Impact of Platinum-Platinum Interactions on Electronic Structure and Carrier Mobilities

Magnus' green salt is the prototype of a class of organic–inorganic hybrid semiconducting materials that combine attractive charge‐transport properties and processability. By using density‐functional‐theory methods, the electronic structure of Magnus' green salt is investigated, in particu...

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Bibliographic Details
Published in:Advanced materials (Weinheim) 2006-08, Vol.18 (15), p.2039-2043
Main Authors: Kim, E.-G., Schmidt, K., Caseri, W. R., Kreouzis, T., Stingelin-Stutzmann, N., Brédas, J.-L.
Format: Article
Language:English
Subjects:
Charge transport
Hybrid materials
Hybrid materials, inorganic–organic
inorganic-organic
Semiconductors
Structure-property relationships
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Summary:Magnus' green salt is the prototype of a class of organic–inorganic hybrid semiconducting materials that combine attractive charge‐transport properties and processability. By using density‐functional‐theory methods, the electronic structure of Magnus' green salt is investigated, in particular the nature of the interplatinum interactions (see figure). In conjunction with time‐of‐flight measurements of the carrier mobilities, key structure–property relationships for these materials are re‐established.
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.200600252