Protective and Flame-Retardant Bifunctional Epoxy-Based Nanocomposite Coating by Intercomponent Synergy between Modified CaAl-LDH and rGO

• Published in: ACS applied materials & interfaces 2024-03, Vol.16 (10), p.13114-13131
• Main Authors: Murtaza, Hassan, Zhao, Jingmao, Tabish, Mohammad, Wang, Jingbao, Mubeen, Muhammad, Zhang, Jingfan, Zhang, Sheng, Fan, Baomin
• Format: Article
• Language: English
• Subjects: Applications of Polymer, Composite, and Coating Materials
• ISSN: 1944-8244; 1944-8252
• DOI: 10.1021/acsami.3c19245

Extensive utilization in various settings poses extra requirements of coatings beyond just anticorrosion properties. Herein, 8-hydroxyquinoline (8-HQ) intercalated CaAl-based layered double hydroxide (CaAl-8HQ-LDH) was loaded on reduced GO (rGO) through a one-pot hydrothermal reaction, which was employed as the nanofiller endowing the epoxy (EP/CaAl-8HQ LDH@rGO) with excellent flame-retardancy while ensuring efficient protection for mild steel. Results of electrochemical impedance spectroscopy (EIS) demonstrated the durability of the EP/CaAl-8HQ LDH@rGO-coated specimen, with the impedance at the lowest frequency (|Z|0.01Hz) maintained as 1.84 × 1010 Ω cm2 after 120 days of immersion in a 3.5 wt % NaCl solution. Even for the scratched EP/CaAl-8HQ LDH@rGO system, only a slight decline in |Z|0.01Hz was observed during 180 h of exposure to the NaCl solution, indicating a self-healing feature supported by salt spray tests. UL-94 burning tests revealed the V-0 rating for EP/CaAl-8HQ LDH@rGO with improved thermostability. Strong physical barrier from two-dimensional rGO and the release of 8-HQ from LDH interlayers accounted for the anticorrosive and self-healing properties. However, O2-concentration dilution and charring-layer promotion governed the flame-retardant behavior of the nanocomposite coating. The intercomponent synergy of nanofillers achieved in this work may provide a useful reference for designing multifunctional coatings.