Molecular structure of ferrocenethiol islands embedded into alkanethiol self-assembled monolayers by UHV-STM

[11‐(Acetylthio)‐1‐oxoundecyl]‐ferrocene and 1,1″‐Dithiobis‐ferrocene are inserted into alkanethiolate self‐assembled monolayers from solution. Upon annealing, the inserted molecules form separated domains, which protrude as islands from the surrounding monolayer. The resulting thin‐films are studie...

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Published in:Physica status solidi. A, Applications and materials science Applications and materials science, 2006-05, Vol.203 (6), p.1448-1452
Main Authors: Müller-Meskamp, L., Lüssem, B., Karthäuser, S., Prikhodovski, S., Homberger, M., Simon, U., Waser, R.
Format: Article
Language:English
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05.65.+b
68.35.Bs
68.37.Ef
73.50.-h
81.07.Nb
81.16.Dn
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Physics
Structure and morphology
thickness
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
Thin film structure and morphology
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container_title Physica status solidi. A, Applications and materials science
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creator Müller-Meskamp, L.
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Waser, R.
description [11‐(Acetylthio)‐1‐oxoundecyl]‐ferrocene and 1,1″‐Dithiobis‐ferrocene are inserted into alkanethiolate self‐assembled monolayers from solution. Upon annealing, the inserted molecules form separated domains, which protrude as islands from the surrounding monolayer. The resulting thin‐films are studied by UHV‐STM. For both compounds the density of the molecules in close packed SAMs is determined. Furthermore for ferroceneundecanethiols the molecular structure and orientation of the endgroups is resolved. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
doi_str_mv 10.1002/pssa.200566148
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subjects 05.65.+b
68.35.Bs
68.37.Ef
73.50.-h
81.07.Nb
81.16.Dn
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Physics
Structure and morphology
thickness
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
Thin film structure and morphology
title Molecular structure of ferrocenethiol islands embedded into alkanethiol self-assembled monolayers by UHV-STM
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