Magnetic structures of [Co 3(pyz)(HPO 4) 2F 2], a fluorinated cobalt phosphate with a pillared layer structutre

The magnetic structure of [Co 3(pyz)(HPO 4) 2F 2] compound was characterized by neutron diffraction. The crystal structure of the compound consists of two-dimensional neutral sheets of [Co 3(HPO 4) 2F 2], which are pillared through pyrazine ligand. Magnetic unit cell size perpendicular to the sheet...

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Bibliographic Details
Published in:Physica. B, Condensed matter Condensed matter, 2006-05, Vol.378, p.1140-1141
Main Authors: Yang, C.C., Lee, S.F., Yao, Y.D., Li, W.-H., Lii, K.H., Lynn, J.W.
Format: Article
Language:English
Subjects:
Antiferromagnetic arrangement
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Layered structure
Magnetic properties and materials
Neutron diffraction
Physics
Spin arrangements in magnetically ordered materials (including neutron and spin-polarized electron studies, synchrotron-source x-ray scattering, etc.)
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Summary:The magnetic structure of [Co 3(pyz)(HPO 4) 2F 2] compound was characterized by neutron diffraction. The crystal structure of the compound consists of two-dimensional neutral sheets of [Co 3(HPO 4) 2F 2], which are pillared through pyrazine ligand. Magnetic unit cell size perpendicular to the sheet plane is twice the interplane distance, indicating an antiferromagnetic arrangement.
ISSN:0921-4526
1873-2135
DOI:10.1016/j.physb.2006.01.457