Molecular Photoelectrochemical Devices: Supramolecular Incorporation of C60 Molecules into Tailored Holes on Porphyrin-Modified Gold Nanoclusters

Organic photovoltaic devices based on supramolecular complexes of porphyrin‐modified gold nanoclusters with fullerene molecules are described and their promising photoelectrochemical performance reported. The incorporation of C60 in surface holes on the porphyrin‐modified gold nanoclusters (see Figu...

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Published in:Advanced materials (Weinheim) 2005-07, Vol.17 (14), p.1727-1730
Main Authors: Imahori, H., Fujimoto, A., Kang, S., Hotta, H., Yoshida, K., Umeyama, T., Matano, Y., Isoda, S.
Format: Article
Language:English
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Fullerenes
Nanoclusters
Photovoltaic devices
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container_issue 14
container_start_page 1727
container_title Advanced materials (Weinheim)
container_volume 17
creator Imahori, H.
Fujimoto, A.
Kang, S.
Hotta, H.
Yoshida, K.
Umeyama, T.
Matano, Y.
Isoda, S.
description Organic photovoltaic devices based on supramolecular complexes of porphyrin‐modified gold nanoclusters with fullerene molecules are described and their promising photoelectrochemical performance reported. The incorporation of C60 in surface holes on the porphyrin‐modified gold nanoclusters (see Figure)—caused by the addition of a short‐chain alkanethiol to the porphyrin modification mixture—plays a key role.
doi_str_mv 10.1002/adma.200401770
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subjects Fullerenes
Nanoclusters
Photovoltaic devices
title Molecular Photoelectrochemical Devices: Supramolecular Incorporation of C60 Molecules into Tailored Holes on Porphyrin-Modified Gold Nanoclusters
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