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Novel electrolyte for zinc–polyaniline batteries
Electrochemical behavior of zinc and polyaniline (PANI) electrode polymerized from 0.1 M HCl and 0.1 M aniline on graphite electrode, in 0.2 M ZnCl 2 and 0.50 M NH 4Cl (chloride electrolyte) and with addition of 0.33 M Na-citrate (chloride/citrate electrolyte) were investigated. In the chloride/citr...
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| Published in: | Journal of power sources 2006-10, Vol.160 (2), p.1447-1450 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c373t-c5f84bd801b94599974493fed5adf9aeea51b5c582f76b11c82594a4c67f5e3 |
| container_end_page | 1450 |
| container_issue | 2 |
| container_start_page | 1447 |
| container_title | Journal of power sources |
| container_volume | 160 |
| creator | Jugović, B.Z. Trišović, T.Lj Stevanović, J. Maksimović, M. Grgur, B.N. |
| description | Electrochemical behavior of zinc and polyaniline (PANI) electrode polymerized from 0.1
M HCl and 0.1
M aniline on graphite electrode, in 0.2
M ZnCl
2 and 0.50
M NH
4Cl (chloride electrolyte) and with addition of 0.33
M Na-citrate (chloride/citrate electrolyte) were investigated. In the chloride/citrate comparing with chloride containing electrolyte for the zinc electrode negative shift of the open circuit potential of 150
mV, decreases of exchange current density for more than order of magnitude and increase of cathodic Tafel slope, due to the zinc ions complexation, were observed. In citrate/chloride electrolyte zinc dendrite formation were completely suppressed. PANI electrodes show better discharge characteristic in chloride/citrate electrolyte with determined maximum discharge capacity of 164
mAh
g
−1. |
| doi_str_mv | 10.1016/j.jpowsour.2006.02.096 |
| format | article |
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M HCl and 0.1
M aniline on graphite electrode, in 0.2
M ZnCl
2 and 0.50
M NH
4Cl (chloride electrolyte) and with addition of 0.33
M Na-citrate (chloride/citrate electrolyte) were investigated. In the chloride/citrate comparing with chloride containing electrolyte for the zinc electrode negative shift of the open circuit potential of 150
mV, decreases of exchange current density for more than order of magnitude and increase of cathodic Tafel slope, due to the zinc ions complexation, were observed. In citrate/chloride electrolyte zinc dendrite formation were completely suppressed. PANI electrodes show better discharge characteristic in chloride/citrate electrolyte with determined maximum discharge capacity of 164
mAh
g
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M HCl and 0.1
M aniline on graphite electrode, in 0.2
M ZnCl
2 and 0.50
M NH
4Cl (chloride electrolyte) and with addition of 0.33
M Na-citrate (chloride/citrate electrolyte) were investigated. In the chloride/citrate comparing with chloride containing electrolyte for the zinc electrode negative shift of the open circuit potential of 150
mV, decreases of exchange current density for more than order of magnitude and increase of cathodic Tafel slope, due to the zinc ions complexation, were observed. In citrate/chloride electrolyte zinc dendrite formation were completely suppressed. PANI electrodes show better discharge characteristic in chloride/citrate electrolyte with determined maximum discharge capacity of 164
mAh
g
−1.</description><subject>Applied sciences</subject><subject>Batteries</subject><subject>Chloride</subject><subject>Citrates</subject><subject>Dendrites</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Exact sciences and technology</subject><subject>Polyaniline</subject><subject>Zinc</subject><issn>0378-7753</issn><issn>1873-2755</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqFkE1OwzAQRi0EEqVwBZQN7BLsOI7tHajiT6pgAXvLccaSIzcudlpUVtyBG3ISUrWIJauRRu_7RvMQOie4IJjUV13RLcN7CqtYlBjXBS4LLOsDNCGC07zkjB2iCaZc5JwzeoxOUuowxoRwPEHlU1iDz8CDGWLwmwEyG2L24Xrz_fm1HDe6d971kDV6GCA6SKfoyGqf4Gw_p-jl7vZ19pDPn-8fZzfz3FBOh9wwK6qmFZg0smJSSl5VklpomW6t1ACakYYZJkrL64YQI0omK12ZmlsGdIoud63LGN5WkAa1cMmA97qHsEqqHEsFZWwE6x1oYkgpglXL6BY6bhTBaitIdepXkNoKUrhUo6AxeLG_oJPR3kbdG5f-0qLChGI-ctc7DsZn1w6iSsZBb6B1cbSm2uD-O_UDp0CBXA</recordid><startdate>20061006</startdate><enddate>20061006</enddate><creator>Jugović, B.Z.</creator><creator>Trišović, T.Lj</creator><creator>Stevanović, J.</creator><creator>Maksimović, M.</creator><creator>Grgur, B.N.</creator><general>Elsevier B.V</general><general>Elsevier Sequoia</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope><scope>KR7</scope><scope>L7M</scope></search><sort><creationdate>20061006</creationdate><title>Novel electrolyte for zinc–polyaniline batteries</title><author>Jugović, B.Z. ; Trišović, T.Lj ; Stevanović, J. ; Maksimović, M. ; Grgur, B.N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c373t-c5f84bd801b94599974493fed5adf9aeea51b5c582f76b11c82594a4c67f5e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Applied sciences</topic><topic>Batteries</topic><topic>Chloride</topic><topic>Citrates</topic><topic>Dendrites</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Exact sciences and technology</topic><topic>Polyaniline</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jugović, B.Z.</creatorcontrib><creatorcontrib>Trišović, T.Lj</creatorcontrib><creatorcontrib>Stevanović, J.</creatorcontrib><creatorcontrib>Maksimović, M.</creatorcontrib><creatorcontrib>Grgur, B.N.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of power sources</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jugović, B.Z.</au><au>Trišović, T.Lj</au><au>Stevanović, J.</au><au>Maksimović, M.</au><au>Grgur, B.N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel electrolyte for zinc–polyaniline batteries</atitle><jtitle>Journal of power sources</jtitle><date>2006-10-06</date><risdate>2006</risdate><volume>160</volume><issue>2</issue><spage>1447</spage><epage>1450</epage><pages>1447-1450</pages><issn>0378-7753</issn><eissn>1873-2755</eissn><coden>JPSODZ</coden><abstract>Electrochemical behavior of zinc and polyaniline (PANI) electrode polymerized from 0.1
M HCl and 0.1
M aniline on graphite electrode, in 0.2
M ZnCl
2 and 0.50
M NH
4Cl (chloride electrolyte) and with addition of 0.33
M Na-citrate (chloride/citrate electrolyte) were investigated. In the chloride/citrate comparing with chloride containing electrolyte for the zinc electrode negative shift of the open circuit potential of 150
mV, decreases of exchange current density for more than order of magnitude and increase of cathodic Tafel slope, due to the zinc ions complexation, were observed. In citrate/chloride electrolyte zinc dendrite formation were completely suppressed. PANI electrodes show better discharge characteristic in chloride/citrate electrolyte with determined maximum discharge capacity of 164
mAh
g
−1.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jpowsour.2006.02.096</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0378-7753 |
| ispartof | Journal of power sources, 2006-10, Vol.160 (2), p.1447-1450 |
| issn | 0378-7753 1873-2755 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_29458355 |
| source | ScienceDirect Journals |
| subjects | Applied sciences Batteries Chloride Citrates Dendrites Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Exact sciences and technology Polyaniline Zinc |
| title | Novel electrolyte for zinc–polyaniline batteries |
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