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Conductivity and thermal behavior of proton conducting polymer electrolyte based on poly ( N-vinyl pyrrolidone)
The polymer electrolytes based on poly N-vinyl pyrrolidone (PVP) and ammonium thiocyanate (NH 4SCN) with different compositions have been prepared by solution casting technique. The amorphous nature of the polymer electrolytes has been confirmed by XRD analysis. The shift in T g values and the melti...
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| Published in: | European polymer journal 2006-10, Vol.42 (10), p.2672-2677 |
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| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c442t-89c9de1bec826ba185a2a3477a47617a750f35a7b8f69922390dfdc1b40d33a03 |
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| cites | cdi_FETCH-LOGICAL-c442t-89c9de1bec826ba185a2a3477a47617a750f35a7b8f69922390dfdc1b40d33a03 |
| container_end_page | 2677 |
| container_issue | 10 |
| container_start_page | 2672 |
| container_title | European polymer journal |
| container_volume | 42 |
| creator | Ramya, C.S. Selvasekarapandian, S. Savitha, T. Hirankumar, G. Baskaran, R. Bhuvaneswari, M.S. Angelo, P.C. |
| description | The polymer electrolytes based on poly
N-vinyl pyrrolidone (PVP) and ammonium thiocyanate (NH
4SCN) with different compositions have been prepared by solution casting technique. The amorphous nature of the polymer electrolytes has been confirmed by XRD analysis. The shift in
T
g values and the melting temperatures of the PVP–NH
4SCN electrolytes shown by DSC thermo-grams indicate an interaction between the polymer and the salt. The dependence of
T
g and conductivity upon salt concentration have been discussed. The conductivity analysis shows that the 20
mol% ammonium thiocyanate doped polymer electrolyte exhibit high ionic conductivity and it has been found to be 1.7
×
10
−4
S
cm
−1, at room temperature. The conductivity values follow the Arrhenius equation and the activation energy for 20
mol% ammonium thiocyanate doped polymer electrolyte has been found to be 0.52
eV. |
| doi_str_mv | 10.1016/j.eurpolymj.2006.05.020 |
| format | article |
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N-vinyl pyrrolidone (PVP) and ammonium thiocyanate (NH
4SCN) with different compositions have been prepared by solution casting technique. The amorphous nature of the polymer electrolytes has been confirmed by XRD analysis. The shift in
T
g values and the melting temperatures of the PVP–NH
4SCN electrolytes shown by DSC thermo-grams indicate an interaction between the polymer and the salt. The dependence of
T
g and conductivity upon salt concentration have been discussed. The conductivity analysis shows that the 20
mol% ammonium thiocyanate doped polymer electrolyte exhibit high ionic conductivity and it has been found to be 1.7
×
10
−4
S
cm
−1, at room temperature. The conductivity values follow the Arrhenius equation and the activation energy for 20
mol% ammonium thiocyanate doped polymer electrolyte has been found to be 0.52
eV.</description><identifier>ISSN: 0014-3057</identifier><identifier>EISSN: 1873-1945</identifier><identifier>DOI: 10.1016/j.eurpolymj.2006.05.020</identifier><identifier>CODEN: EUPJAG</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Activation energy ; Applied sciences ; Conductivity analysis ; Electrical, magnetic and optical properties ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Poly ( N-vinyl pyrrolidone) ; Properties and characterization ; Proton conductor</subject><ispartof>European polymer journal, 2006-10, Vol.42 (10), p.2672-2677</ispartof><rights>2006 Elsevier Ltd</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c442t-89c9de1bec826ba185a2a3477a47617a750f35a7b8f69922390dfdc1b40d33a03</citedby><cites>FETCH-LOGICAL-c442t-89c9de1bec826ba185a2a3477a47617a750f35a7b8f69922390dfdc1b40d33a03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=18168877$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Ramya, C.S.</creatorcontrib><creatorcontrib>Selvasekarapandian, S.</creatorcontrib><creatorcontrib>Savitha, T.</creatorcontrib><creatorcontrib>Hirankumar, G.</creatorcontrib><creatorcontrib>Baskaran, R.</creatorcontrib><creatorcontrib>Bhuvaneswari, M.S.</creatorcontrib><creatorcontrib>Angelo, P.C.</creatorcontrib><title>Conductivity and thermal behavior of proton conducting polymer electrolyte based on poly ( N-vinyl pyrrolidone)</title><title>European polymer journal</title><description>The polymer electrolytes based on poly
N-vinyl pyrrolidone (PVP) and ammonium thiocyanate (NH
4SCN) with different compositions have been prepared by solution casting technique. The amorphous nature of the polymer electrolytes has been confirmed by XRD analysis. The shift in
T
g values and the melting temperatures of the PVP–NH
4SCN electrolytes shown by DSC thermo-grams indicate an interaction between the polymer and the salt. The dependence of
T
g and conductivity upon salt concentration have been discussed. The conductivity analysis shows that the 20
mol% ammonium thiocyanate doped polymer electrolyte exhibit high ionic conductivity and it has been found to be 1.7
×
10
−4
S
cm
−1, at room temperature. The conductivity values follow the Arrhenius equation and the activation energy for 20
mol% ammonium thiocyanate doped polymer electrolyte has been found to be 0.52
eV.</description><subject>Activation energy</subject><subject>Applied sciences</subject><subject>Conductivity analysis</subject><subject>Electrical, magnetic and optical properties</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Poly ( N-vinyl pyrrolidone)</subject><subject>Properties and characterization</subject><subject>Proton conductor</subject><issn>0014-3057</issn><issn>1873-1945</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqFkMGO0zAQhi0EEmXhGfAFBIeEsZ3EyXFVLSzSCi5wtib2hHWV2sVOK-XtcWkFxz1ZI3___PbH2FsBtQDRfdrVdEyHOK_7XS0BuhraGiQ8YxvRa1WJoWmfsw2AaCoFrX7JXuW8AwCtOrVhcRuDO9rFn_yycgyOL4-U9jjzkR7x5GPiceKHFJcYuL2y4Rf_W0iJ00x2SWVYiI-YyfHCnS_5B_6tOvmwzvywpkJ4FwN9fM1eTDhnenM9b9jPz3c_tvfVw_cvX7e3D5VtGrlU_WAHR2Ik28tuRNG3KFE1WmOjO6FRtzCpFvXYT90wSKkGcJOzYmzAKYWgbtj7y97y9N9HyovZ-2xpnjFQPGYjh6bEpCigvoA2xZwTTeaQ_B7TagSYs2CzM_8Em7NgA60pgkvy3bUCs8V5Shisz__jvej6XuvC3V44Kv89eUomW0_BkvOpyDMu-ie7_gDmGJgH</recordid><startdate>20061001</startdate><enddate>20061001</enddate><creator>Ramya, C.S.</creator><creator>Selvasekarapandian, S.</creator><creator>Savitha, T.</creator><creator>Hirankumar, G.</creator><creator>Baskaran, R.</creator><creator>Bhuvaneswari, M.S.</creator><creator>Angelo, P.C.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20061001</creationdate><title>Conductivity and thermal behavior of proton conducting polymer electrolyte based on poly ( N-vinyl pyrrolidone)</title><author>Ramya, C.S. ; Selvasekarapandian, S. ; Savitha, T. ; Hirankumar, G. ; Baskaran, R. ; Bhuvaneswari, M.S. ; Angelo, P.C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c442t-89c9de1bec826ba185a2a3477a47617a750f35a7b8f69922390dfdc1b40d33a03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Activation energy</topic><topic>Applied sciences</topic><topic>Conductivity analysis</topic><topic>Electrical, magnetic and optical properties</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Poly ( N-vinyl pyrrolidone)</topic><topic>Properties and characterization</topic><topic>Proton conductor</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ramya, C.S.</creatorcontrib><creatorcontrib>Selvasekarapandian, S.</creatorcontrib><creatorcontrib>Savitha, T.</creatorcontrib><creatorcontrib>Hirankumar, G.</creatorcontrib><creatorcontrib>Baskaran, R.</creatorcontrib><creatorcontrib>Bhuvaneswari, M.S.</creatorcontrib><creatorcontrib>Angelo, P.C.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>European polymer journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ramya, C.S.</au><au>Selvasekarapandian, S.</au><au>Savitha, T.</au><au>Hirankumar, G.</au><au>Baskaran, R.</au><au>Bhuvaneswari, M.S.</au><au>Angelo, P.C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Conductivity and thermal behavior of proton conducting polymer electrolyte based on poly ( N-vinyl pyrrolidone)</atitle><jtitle>European polymer journal</jtitle><date>2006-10-01</date><risdate>2006</risdate><volume>42</volume><issue>10</issue><spage>2672</spage><epage>2677</epage><pages>2672-2677</pages><issn>0014-3057</issn><eissn>1873-1945</eissn><coden>EUPJAG</coden><abstract>The polymer electrolytes based on poly
N-vinyl pyrrolidone (PVP) and ammonium thiocyanate (NH
4SCN) with different compositions have been prepared by solution casting technique. The amorphous nature of the polymer electrolytes has been confirmed by XRD analysis. The shift in
T
g values and the melting temperatures of the PVP–NH
4SCN electrolytes shown by DSC thermo-grams indicate an interaction between the polymer and the salt. The dependence of
T
g and conductivity upon salt concentration have been discussed. The conductivity analysis shows that the 20
mol% ammonium thiocyanate doped polymer electrolyte exhibit high ionic conductivity and it has been found to be 1.7
×
10
−4
S
cm
−1, at room temperature. The conductivity values follow the Arrhenius equation and the activation energy for 20
mol% ammonium thiocyanate doped polymer electrolyte has been found to be 0.52
eV.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.eurpolymj.2006.05.020</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0014-3057 |
| ispartof | European polymer journal, 2006-10, Vol.42 (10), p.2672-2677 |
| issn | 0014-3057 1873-1945 |
| language | eng |
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| source | ScienceDirect Freedom Collection 2022-2024 |
| subjects | Activation energy Applied sciences Conductivity analysis Electrical, magnetic and optical properties Exact sciences and technology Organic polymers Physicochemistry of polymers Poly ( N-vinyl pyrrolidone) Properties and characterization Proton conductor |
| title | Conductivity and thermal behavior of proton conducting polymer electrolyte based on poly ( N-vinyl pyrrolidone) |
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