Chromium-exchanged zeolite (Cr E-ZSM-5) as catalyst for alcohol oxidation and benzylic oxidation with t-BuOOH

The oxidative properties of chromium-exchanged zeolite (Cr E-ZSM-5) towards the oxidation of alcohols and benzylic methylene groups with t-butyl hydroperoxide have been evaluated. In most cases, high yields of ketones have been obtained. Experimental evidence is presented that these reactions were,...

Full description

Saved in:
Bibliographic Details
Published in:Applied catalysis. A, General General, 2006-08, Vol.309 (2), p.270-272
Main Authors: Lounis, Zoubida, Riahi, Abdelkhalek, Djafri, Fatiha, Muzart, Jacques
Format: Article
Language:English
Subjects:
Alcohol oxidation
Benzylic oxidation
Catalysis
Chemistry
Chromium-exchanged zeolite
Cr E-ZSM-5
Exact sciences and technology
General and physical chemistry
Ion-exchange
Leaching
Surface physical chemistry
t-Butyl hydroperoxide
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Zeolites: preparations and properties
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The oxidative properties of chromium-exchanged zeolite (Cr E-ZSM-5) towards the oxidation of alcohols and benzylic methylene groups with t-butyl hydroperoxide have been evaluated. In most cases, high yields of ketones have been obtained. Experimental evidence is presented that these reactions were, at least in part, homogeneously catalyzed by leached chromium.
ISSN:0926-860X
1873-3875
DOI:10.1016/j.apcata.2006.05.015