Catalytic wet peroxide oxidation of phenol with a Fe/active carbon catalyst

• Published in: Applied catalysis. B, Environmental Environmental, 2006-06, Vol.65 (3-4), p.261-268
• Main Authors: Zazo, J.A., Casas, J.A., Mohedano, A.F., Rodríguez, J.J.
• Format: Article
• Language: English
• Subjects: Active carbon iron supported catalyst; Adsorbents; Catalysis; Chemistry; CWPO; Exact sciences and technology; Fe/AC; General and physical chemistry; Hydrogen peroxide; Phenol oxidation; Surface physical chemistry; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
• ISSN: 0926-3373; 1873-3883
• DOI: 10.1016/j.apcatb.2006.02.008

A Fe on activated carbon catalyst has been prepared and tested for phenol oxidation with H2O2 in aqueous solution at low concentration (100mg/L). Working at 50°C, initial pH 3 and a dose of H2O2 corresponding to the stoichiometric amount (500mg/L) complete removal of phenol and a high TOC reduction (around 85%) has been reached. Oxidation of phenol gives rise to highly toxic aromatic intermediates which finally disappear completely evolving to short-chain organic acids. Some of these last showed to be fairly resistant to oxidation being responsible for the residual TOC. In long-term continuous experiments the catalyst undergoes a significant loss of activity in a relatively short term (20–25h) due to Fe leaching, this being related with the amount of oxalic acid produced. Deactivation may also be caused by active sites blockage due to polymeric deposits on whose formation some evidences were found. Washing with 1N NaOH solution allows to recover the activity although complete restoration was not achieved.