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Corrosion of copper and silver plates by volcanic gases

Corrosion products that had been formed on copper and silver plates exposed in Miyake Island, where suffered a volcanic eruption in 2000, were analyzed by X-ray techniques to get better understanding of copper and silver corrosion in harsh environment. The exposure experiment was carried out from Se...

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Published in:Corrosion science 2006-11, Vol.48 (11), p.3759-3766
Main Authors: Watanabe, Masamitsu, Hokazono, Akira, Handa, Takao, Ichino, Toshihiro, Kuwaki, Nobuo
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Language:English
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container_end_page 3766
container_issue 11
container_start_page 3759
container_title Corrosion science
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creator Watanabe, Masamitsu
Hokazono, Akira
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Kuwaki, Nobuo
description Corrosion products that had been formed on copper and silver plates exposed in Miyake Island, where suffered a volcanic eruption in 2000, were analyzed by X-ray techniques to get better understanding of copper and silver corrosion in harsh environment. The exposure experiment was carried out from September 2004 to April 2005. Many kinds of patina were found on copper such as cuprite (Cu 2O), posnjakite (Cu 4SO 4(OH) 6 · H 2O), brochantite (Cu 4SO 4(OH) 6), antlerite (Cu 3SO 4(OH) 4), and geerite (Cu 8S 5). For silver, silver chloride (AgCl) and silver sulfide (Ag 2S) were formed. Although the volcanic activity had greatly subsided, the atmospheric corrosion of copper and silver plates exposed on Miyake Island was mainly affected by volcanic gases, wet–dry cycles in the environment, and sea-salt aerosols.
doi_str_mv 10.1016/j.corsci.2005.12.009
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1879-0496
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source Elsevier
subjects A. Copper
A. Silver
Applied sciences
B. X-ray fluorescence analysis (XRF)
B. XRD
C. Atmospheric corrosion
Corrosion
Corrosion environments
Exact sciences and technology
Metals. Metallurgy
title Corrosion of copper and silver plates by volcanic gases
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