Synthesis and characterization of a main-chain-type conjugated copolymer containing rare earth with photocrosslinkable group

In this article, we report the design, synthesis, and characterization of a new main‐chain‐type rare earth‐containing conjugated polymer with photocrosslinkable group. The polymer is crosslinked photochemically by the addition of a photoinitiator to yield an absolute insoluble network. The optical p...

Full description

Saved in:
Bibliographic Details
Published in:Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2007-02, Vol.45 (3), p.388-394
Main Authors: Wen, Gui-An, Zhu, Xing-Rong, Wang, Lian-Hui, Feng, Jia-Chun, Zhu, Rui, Wei, Wei, PEng, Bo, Pei, Qi-Bing, Huang, Wei
Format: Article
Language:English
Subjects:
Applied sciences
conjugated polymer
crosslinking
energy transfer
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymers with particular properties
Preparation, kinetics, thermodynamics, mechanism and catalysts
rare earth
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:In this article, we report the design, synthesis, and characterization of a new main‐chain‐type rare earth‐containing conjugated polymer with photocrosslinkable group. The polymer is crosslinked photochemically by the addition of a photoinitiator to yield an absolute insoluble network. The optical properties of the resulting conjugated polymer were characterized in solution, film state, and after photocrosslinking. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 388–394, 2007. A main‐chain‐type rare earth‐containing conjugated polymer, which can be crosslinked photochemically into insoluble film, was prepared by suzuki polycondensation and further complexation with rare earth triisopropyloxide and beta‐diketone. The optical properties of the resulting conjugated polymer were characterized in solution, film state, and after photocrosslinking.
ISSN:0887-624X
1099-0518
DOI:10.1002/pola.21723