Thermochemical properties of composites of synthetic zeolite ZSM5 and silver iodide

Thermochemical properties of two kinds of composite material of synthetic zeolite ZSM5 in potassium form (K-ZSM5) with AgI have been studied. The composites have been prepared by treating the silver form of synthetic zeolite ZSM5 (Ag-ZSM5) with potassium iodide solution under different experimental...

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Published in:Journal of Thermal Analysis and Calorimetry 2006-05, Vol.84 (3), p.721-726
Main Authors: CUVANOVA, S, REHAKOVA, M, BASTL, Z, POLLICINO, A, NAGYOVA, S, FAJNOR, V. S
Format: Article
Language:English
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Chemistry
Exact sciences and technology
General and physical chemistry
Ion-exchange
Surface physical chemistry
Zeolites: preparations and properties
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description Thermochemical properties of two kinds of composite material of synthetic zeolite ZSM5 in potassium form (K-ZSM5) with AgI have been studied. The composites have been prepared by treating the silver form of synthetic zeolite ZSM5 (Ag-ZSM5) with potassium iodide solution under different experimental conditions. One of the composites was additionally sintered at temperature 500 deg C for 20 h. Both composites have been characterized by TG, DTG, DTA, EDS analysis, X-ray powder diffractometry and X-ray photoelectron spectroscopy. The methods of thermal analysis as well as X-ray powder diffractometry and XPS confirmed the differences between the two composites caused by sintering during the synthesis. The content of AgI in the surface layer was different. No changes of the zeolitic mineral dimensions are observed.
doi_str_mv 10.1007/s10973-005-7541-7
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subjects Chemistry
Exact sciences and technology
General and physical chemistry
Ion-exchange
Surface physical chemistry
Zeolites: preparations and properties
title Thermochemical properties of composites of synthetic zeolite ZSM5 and silver iodide
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