Studies of the lithium ion transport properties in electrolytic molybdenum oxides

Transport properties of the electrolytic oxide Mo 4O 11 proposed as the cathode material of lithium power sources are discussed. On the basis of the mathematical diffusion models of intercalation/deintercalation under the conditions of cyclic voltammetry and galvanostatic mode, the average value of...

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Bibliographic Details
Published in:Solid state ionics 2004-04, Vol.169 (1), p.135-137
Main Authors: Tysyachny, V.P., Shembel, E.M., Apostolova, R.D., Nagirny, V.M., Kylyvnyk, K.E., Eskova, N.I.
Format: Article
Language:English
Subjects:
Diffusion in solids
Electrolytic Mo-oxide
Intercalation of Li
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Summary:Transport properties of the electrolytic oxide Mo 4O 11 proposed as the cathode material of lithium power sources are discussed. On the basis of the mathematical diffusion models of intercalation/deintercalation under the conditions of cyclic voltammetry and galvanostatic mode, the average value of the chemical diffusion coefficient of Li + has been determined as equal to 1.3–6.4×10 −12 cm 2/s.
ISSN:0167-2738
1872-7689
DOI:10.1016/S0167-2738(03)00184-X