Structural and magnetic properties of nanocrystalline Nd4.5Fe72Co2Cr3Al1B17.5 ribbons

• Published in: Physica. B, Condensed matter Condensed matter, 2007-02, Vol.389 (1), p.172-175
• Main Authors: PAMPILLO, L. G, SACCONE, F. D, SIRKIN, H. R. M
• Format: Article
• Language: English
• Subjects: Condensed matter: electronic structure, electrical, magnetic, and optical properties; Exact sciences and technology; Magnetic properties and materials; Magnetic properties of nanostructures; Magnetic resonances and relaxations in condensed matter, mössbauer effect; Mössbauer effect; other γ-ray spectroscopy; Physics
• ISSN: 0921-4526; 1873-2135
• DOI: 10.1016/j.physb.2006.07.050

In this work, it was made a study on structural and magnetic properties of nanocrystalline Nd4.5Fe72Co2Cr3Al1B17.5 ribbons obtained from crystallisation of amorphous precursors. A complex two-step crystallisation process, was found by differential scanning calorimetry (DSC): a first crystallisation peak at around T=570 deg C exhibiting the precipitation of alpha-Fe and t-Fe3B phases and a diffusive stage ending in a second exothermic peak. Also, isothermal annealings of 10min duration were performed at 605, 635, 650 and 685 deg C.Hysteresis curves of isothermally annealed samples showed magnetic hardening, with coercive fields above 2kOe and an optimised MR/MS ratio of around 0.6. Except for the highest treatment temperature used in this work, the demagnetizing curves of annealed ribbons exhibited a step near zero field. This fact suggests a low exchange coupling between hard and soft phases, which can be attributed to the grain border phases. Otherwise, Mossbauer effect spectroscopy allowed us to determine that the absence of step in the demagnetizing curve of ribbons annealed at 685 deg C, may be attributed to the formation of a alpha-(Fe, Co) solid solution (with hyperfine parameters BHF=35.5T and delta=-0.11mm/s). The formation of this solid solution also explains the diffusive process in the second crystallisation stage observed by DSC experiment.