The “filler-effect” in organic ionic plastic crystals: Enhanced conductivity by the addition of nano-sized TiO2

The addition of nano-sized ceramic particles to the plastic crystal ethyl-methyl pyrrolidinium bis(trifluoromethane sulfonyl)amide (P12TFSA) has been investigated by means of DSC and conductivity. The thermal behaviour of the plastic crystal as a function of filler content suggests that the filler p...

Full description

Saved in:
Bibliographic Details
Published in:Solid state ionics 2006-03, Vol.177 (9-10), p.827-831
Main Authors: ADEBAHR, J, CICCOSILLO, N, SHEKIBI, Y, MACFARLANE, D, HILL, A, FORSYTH, M
Format: Article
Language:English
Citations: Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c342t-b2f67a187d62cbd50a5b5df8239ac63bf2382573d7f3d68f037b3e70edf25dae3
cites
container_end_page 831
container_issue 9-10
container_start_page 827
container_title Solid state ionics
container_volume 177
creator ADEBAHR, J
CICCOSILLO, N
SHEKIBI, Y
MACFARLANE, D
HILL, A
FORSYTH, M
description The addition of nano-sized ceramic particles to the plastic crystal ethyl-methyl pyrrolidinium bis(trifluoromethane sulfonyl)amide (P12TFSA) has been investigated by means of DSC and conductivity. The thermal behaviour of the plastic crystal as a function of filler content suggests that the filler particles decrease the onset temperature of the melting slightly at high loadings, however they do not decrease the crystallinity of the material. Furthermore, the IV - > III transition decreases in intensity, indicating that the addition of filler increases the possibility for the crystal to remain in metastable rotator phases also at lower temperatures. The conductivity shows a more than one order of magnitude increase with the addition of filler, with a filler concentration dependence that levels out above 10wt.% TiO2.
doi_str_mv 10.1016/j.ssi.2006.02.022
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_29712174</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>29712174</sourcerecordid><originalsourceid>FETCH-LOGICAL-c342t-b2f67a187d62cbd50a5b5df8239ac63bf2382573d7f3d68f037b3e70edf25dae3</originalsourceid><addsrcrecordid>eNotkD1OAzEQhV2ARAgcgM4V3S72OLve0KEo_EiR0oTa8vqHONrYYe0gLVUOApfLSXAUpKd50sybr3gI3VFSUkLrh00ZoyuBkLokkAUXaJT3vADOmit0HeOG5CNr6hGKq7XBx8OPdV1n-sJYa1Q6Hn6x8zj0H9I7hV04zV0nY8qu-iEm2cVHPPdr6ZXRWAWv9yq5L5cG3A44ZabU2qX8iYPFXvpQRPedoyu3hBt0aTPA3P77GL0_z1ez12KxfHmbPS0KxSaQihZszSVtuK5BtboismorbRtgU6lq1lpgDVScaW6ZrhtLGG-Z4cRoC5WWho3R_Zm768Pn3sQkti4q03XSm7CPAqacAuWTHKTnoOpDjL2xYte7rewHQYk4VSo2IlcqTpUKAlnA_gAsxXCa</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>29712174</pqid></control><display><type>article</type><title>The “filler-effect” in organic ionic plastic crystals: Enhanced conductivity by the addition of nano-sized TiO2</title><source>ScienceDirect Freedom Collection 2022-2024</source><creator>ADEBAHR, J ; CICCOSILLO, N ; SHEKIBI, Y ; MACFARLANE, D ; HILL, A ; FORSYTH, M</creator><creatorcontrib>ADEBAHR, J ; CICCOSILLO, N ; SHEKIBI, Y ; MACFARLANE, D ; HILL, A ; FORSYTH, M</creatorcontrib><description>The addition of nano-sized ceramic particles to the plastic crystal ethyl-methyl pyrrolidinium bis(trifluoromethane sulfonyl)amide (P12TFSA) has been investigated by means of DSC and conductivity. The thermal behaviour of the plastic crystal as a function of filler content suggests that the filler particles decrease the onset temperature of the melting slightly at high loadings, however they do not decrease the crystallinity of the material. Furthermore, the IV - &gt; III transition decreases in intensity, indicating that the addition of filler increases the possibility for the crystal to remain in metastable rotator phases also at lower temperatures. The conductivity shows a more than one order of magnitude increase with the addition of filler, with a filler concentration dependence that levels out above 10wt.% TiO2.</description><identifier>ISSN: 0167-2738</identifier><identifier>DOI: 10.1016/j.ssi.2006.02.022</identifier><language>eng</language><ispartof>Solid state ionics, 2006-03, Vol.177 (9-10), p.827-831</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c342t-b2f67a187d62cbd50a5b5df8239ac63bf2382573d7f3d68f037b3e70edf25dae3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>ADEBAHR, J</creatorcontrib><creatorcontrib>CICCOSILLO, N</creatorcontrib><creatorcontrib>SHEKIBI, Y</creatorcontrib><creatorcontrib>MACFARLANE, D</creatorcontrib><creatorcontrib>HILL, A</creatorcontrib><creatorcontrib>FORSYTH, M</creatorcontrib><title>The “filler-effect” in organic ionic plastic crystals: Enhanced conductivity by the addition of nano-sized TiO2</title><title>Solid state ionics</title><description>The addition of nano-sized ceramic particles to the plastic crystal ethyl-methyl pyrrolidinium bis(trifluoromethane sulfonyl)amide (P12TFSA) has been investigated by means of DSC and conductivity. The thermal behaviour of the plastic crystal as a function of filler content suggests that the filler particles decrease the onset temperature of the melting slightly at high loadings, however they do not decrease the crystallinity of the material. Furthermore, the IV - &gt; III transition decreases in intensity, indicating that the addition of filler increases the possibility for the crystal to remain in metastable rotator phases also at lower temperatures. The conductivity shows a more than one order of magnitude increase with the addition of filler, with a filler concentration dependence that levels out above 10wt.% TiO2.</description><issn>0167-2738</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNotkD1OAzEQhV2ARAgcgM4V3S72OLve0KEo_EiR0oTa8vqHONrYYe0gLVUOApfLSXAUpKd50sybr3gI3VFSUkLrh00ZoyuBkLokkAUXaJT3vADOmit0HeOG5CNr6hGKq7XBx8OPdV1n-sJYa1Q6Hn6x8zj0H9I7hV04zV0nY8qu-iEm2cVHPPdr6ZXRWAWv9yq5L5cG3A44ZabU2qX8iYPFXvpQRPedoyu3hBt0aTPA3P77GL0_z1ez12KxfHmbPS0KxSaQihZszSVtuK5BtboismorbRtgU6lq1lpgDVScaW6ZrhtLGG-Z4cRoC5WWho3R_Zm768Pn3sQkti4q03XSm7CPAqacAuWTHKTnoOpDjL2xYte7rewHQYk4VSo2IlcqTpUKAlnA_gAsxXCa</recordid><startdate>20060331</startdate><enddate>20060331</enddate><creator>ADEBAHR, J</creator><creator>CICCOSILLO, N</creator><creator>SHEKIBI, Y</creator><creator>MACFARLANE, D</creator><creator>HILL, A</creator><creator>FORSYTH, M</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20060331</creationdate><title>The “filler-effect” in organic ionic plastic crystals: Enhanced conductivity by the addition of nano-sized TiO2</title><author>ADEBAHR, J ; CICCOSILLO, N ; SHEKIBI, Y ; MACFARLANE, D ; HILL, A ; FORSYTH, M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c342t-b2f67a187d62cbd50a5b5df8239ac63bf2382573d7f3d68f037b3e70edf25dae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>ADEBAHR, J</creatorcontrib><creatorcontrib>CICCOSILLO, N</creatorcontrib><creatorcontrib>SHEKIBI, Y</creatorcontrib><creatorcontrib>MACFARLANE, D</creatorcontrib><creatorcontrib>HILL, A</creatorcontrib><creatorcontrib>FORSYTH, M</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Solid state ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>ADEBAHR, J</au><au>CICCOSILLO, N</au><au>SHEKIBI, Y</au><au>MACFARLANE, D</au><au>HILL, A</au><au>FORSYTH, M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The “filler-effect” in organic ionic plastic crystals: Enhanced conductivity by the addition of nano-sized TiO2</atitle><jtitle>Solid state ionics</jtitle><date>2006-03-31</date><risdate>2006</risdate><volume>177</volume><issue>9-10</issue><spage>827</spage><epage>831</epage><pages>827-831</pages><issn>0167-2738</issn><abstract>The addition of nano-sized ceramic particles to the plastic crystal ethyl-methyl pyrrolidinium bis(trifluoromethane sulfonyl)amide (P12TFSA) has been investigated by means of DSC and conductivity. The thermal behaviour of the plastic crystal as a function of filler content suggests that the filler particles decrease the onset temperature of the melting slightly at high loadings, however they do not decrease the crystallinity of the material. Furthermore, the IV - &gt; III transition decreases in intensity, indicating that the addition of filler increases the possibility for the crystal to remain in metastable rotator phases also at lower temperatures. The conductivity shows a more than one order of magnitude increase with the addition of filler, with a filler concentration dependence that levels out above 10wt.% TiO2.</abstract><doi>10.1016/j.ssi.2006.02.022</doi><tpages>5</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0167-2738
ispartof Solid state ionics, 2006-03, Vol.177 (9-10), p.827-831
issn 0167-2738
language eng
recordid cdi_proquest_miscellaneous_29712174
source ScienceDirect Freedom Collection 2022-2024
title The “filler-effect” in organic ionic plastic crystals: Enhanced conductivity by the addition of nano-sized TiO2
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-02T20%3A13%3A58IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20%E2%80%9Cfiller-effect%E2%80%9D%20in%20organic%20ionic%20plastic%20crystals:%20Enhanced%20conductivity%20by%20the%20addition%20of%20nano-sized%20TiO2&rft.jtitle=Solid%20state%20ionics&rft.au=ADEBAHR,%20J&rft.date=2006-03-31&rft.volume=177&rft.issue=9-10&rft.spage=827&rft.epage=831&rft.pages=827-831&rft.issn=0167-2738&rft_id=info:doi/10.1016/j.ssi.2006.02.022&rft_dat=%3Cproquest_cross%3E29712174%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c342t-b2f67a187d62cbd50a5b5df8239ac63bf2382573d7f3d68f037b3e70edf25dae3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=29712174&rft_id=info:pmid/&rfr_iscdi=true